A Temperatural Semi-Memorized Phase Transition in a 1D Organic-Inorganic Hybrid Material of SbIII-Based [(CH2)3NH2S]2SbCl5

The hybrid organic-inorganic materials have received extraordinary attention from the academic community not only because of their natural chemical tunability but also because of their potential in producing exotic physical properties. However, these characteristics are usually caused by the phase transition of materials under changing of external terms, and it is crucial to fully understand their origins. Here, we research an unusual phase transition near room temperature between two ordered phases in a one-dimensional (1D) hybrid organic-inorganic material of Sb-III-based [(CH2)(3)NH2S](2)SbCl5 (1). This phase transition is caused by collective actions, including the primary variation in the bonds of inorganic five-coordinated tetragonal pyramids, displacement and rotation of organic and inorganic components, along with concurrent hydrogen bonds transformation. Afterward, we observe a significant dielectric anomaly at low frequencies between low and high temperatures. This attributed to the fact that two phases coexist with the lessening temperature, which means that a small number of high-temperature features remained but did not occur during the heating process. These findings offer an avenue for inventing a fresh phase transition and dielectric switch hybrid materials, which further open up the prospect for their practical application.