Benzothiazoline: Highly Efficient Reducing Agent for the Enantioselective Organocatalytic Transfer Hydrogenation of Ketimines

被引：140

作者：

Zhu, Chen ^{[1
]}

Akiyama, Takahiko ^{[1
]}

机构：

[1] Gakushuin Univ, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 18期

基金：

日本学术振兴会;

关键词：

CHIRAL BRONSTED ACID; ASYMMETRIC TRANSFER HYDROGENATION; ALPHA-IMINO ESTERS; PHOSPHORIC-ACID; CONJUGATE REDUCTION; CASCADE REACTION; METAL-FREE; CATALYSIS; 2-PHENYLBENZOTHIAZOLINE; HYDROPHOSPHONYLATION;

D O I：

10.1021/ol901762g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzothiazoline proved to be an efficient reducing agent for the phosphoric acid-catalyzed enantioselective transfer hydrogenation reaction of imines. Corresponding amines were obtained with excellent enantioselectivities.

引用

页码：4180 / 4183

页数：4

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