Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5-)-κ2O4,O5]bis(1,10-phenanthroline-κ2N,N′)dysprosium(III) dihydrate

被引：2

作者：

Liu, Xianlin ^{[1
]}

Xing, Huihui ^{[1
]}

Miao, Jing ^{[1
]}

Jia, Maomao ^{[1
]}

Chen, Zilu ^{[1
]}

机构：

[1] Guangxi Normal Univ, Coll Chem & Chem Engn, Guilin 541004, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

CRYSTAL-STRUCTURE; ISOOROTIC ACID; COMPLEX;

D O I：

10.1107/S1600536809036848

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Dy(C5H2.5N2O4)(2)(C12H8N2)(2)]center dot 2H(2)O, the Dy-III ion is located on a twofold rotation axis and is coordinated in a square-antiprismatic geometry by two chelating 1,10-phenanthroline molecules as well as two 4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5-) anions. N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N-H center dot center dot center dot N hydrogen bond is disordered around a twofold rotation axis.

引用

页码：M1224 / +

页数：12

共 18 条

[1]

[Anonymous], 2004, APEX2 SAINT

[2] Supramolecular synthesis of some molecular adducts of 4,4′-bipyridine N,N′-dioxide [J].

Arora, Kapildev K. ;

Talwelkar, Mayura S. ;

Pedireddi, V. R. .

NEW JOURNAL OF CHEMISTRY, 2009, 33 (01) :57-63

[3] Crystal structure, Raman and Fe-57 Mossbauer spectra of the Fe-II complex of iso-orotic acid [J].

Baran, EJ ;

Mercader, RC ;

HuesoUrena, F ;

MorenoCarretero, MN ;

QuirosOlozabal, M ;

SalasPeregrin, JM .

POLYHEDRON, 1996, 15 (10) :1717-1721

[4]

*BRUK AXS INC, 1998, SADABS

[5] Dichloro-(1,10-phenanthroline)(benzene-1,2-diamine)nickel(II) methanol solvate [J].

Chen, ZL ;

Zhang, YZ ;

Liang, FP .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 :M1296-M1297

[6] Spectral and magnetic properties, and biological activity of several coordination compounds of dinegative isoorotato and 2-thioisoorotato ligands. Crystal structure of the tetrameric complex [Cu-4(isoorotato(2-))(4)(NH3)(4)(H2O)(2)]center dot 4H(2)O [J].

HuesoUrena, F ;

MorenoCarretero, MN ;

QuirosOlozabal, M ;

SalasPeregrin, JM ;

Faure, R ;

deCienfuegosLopez, GA .

INORGANICA CHIMICA ACTA, 1996, 241 (02) :61-69

[7] TRANSITION-METAL COMPLEXES WITH MONODEPROTONATED ISOOROTIC AND 2-THIOISOOROTIC ACIDS - CRYSTAL-STRUCTURE, SPECTRAL AND MAGNETIC STUDY, AND ANTIMICROBIAL ACTIVITY [J].

HUESOURENA, F ;

MORENOCARRETERO, MN ;

ROMEROMOLINA, MA ;

SALASPEREGRIN, JM ;

SANCHEZSANCHEZ, MP ;

ALVAREZDECIENFUEGOSLOPEZ, G ;

FAURE, R .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1993, 51 (03) :613-632

[8] N-H•••O and O-H•••O hydrogen-bonded supramolecular networks in 4-chloroanilinium, 2-hydroxyanilinium and 3-hydroxyanilinium hydrogen phthalates [J].

Jagan, R. ;

Sivakumar, K. .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 :O414-O418

[9]

Luo JH, 2002, CHINESE J STRUC CHEM, V21, P392

[10] SYNTHESIS AND STRUCTURE OF AMMONIUM ISOOROTATE MONOHYDRATE AND BIS(ISOOROTATO)-MANGANESE(II) DIHYDRATE [J].

MAISTRALIS, G ;

KATSAROS, N ;

MENTZAFOS, D ;

TERZIS, A .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :740-743

← 1 2 →