Effect of short time ball milling on physicochemical and adsorption performance of activated carbon prepared from mangosteen peel waste

被引：40
作者：
Nasrullah, Asma [1 ,2 ]
Khan, Amir Sada [3 ]
Bhat, A. H. [4 ]
Din, Israf Ud [5 ]
Inayat, Abrar [6 ]
Muhammad, Nawshad [7 ]
Bakhsh, Esraa M. [8 ]
Khan, Sher Bahadar [8 ]
机构：
[1] Univ Teknol PETRONAS, Fundamental & Appl Sci Dept, Bandar Seri Iskandar 32610, Perak, Malaysia
[2] Univ Peshawar, Natl Ctr Excellence Phys Chem, Peshawar 25120, Pakistan
[3] Univ Sci & Technol, Dept Chem, Bannu 28100, Khyber Pakhtunk, Pakistan
[4] Higher Coll Technol, Dept Appl Sci, Muscat 133, Oman
[5] Prince Sattam Bin Abdulaziz Univ, Coll Sci & Humanities, Dept Chem, POB 173, Al Kharj, Saudi Arabia
[6] Univ Sharjah, Dept Sustainable & Renewable Energy Engn, POB 27272, Sharjah, U Arab Emirates
[7] COMSATS Univ Islamabad, Interdisciplinary Res Ctr Biomed Mat IRCBM, Lahore Campus, Lahore, Pakistan
[8] King Abdulaziz Univ, Fac Sci, Chem Dept, POB 80203, Jeddah 21589, Saudi Arabia
来源：
RENEWABLE ENERGY | 2021年 / 168卷
关键词：
Activated carbon; Ball milling; Adsorption kinetics; Isotherm model; Thermodynamics;
D O I：
10.1016/j.renene.2020.12.077
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
This study investigates the short time ball milling effect on surface properties of activated carbon. (AC) produced from mangosteen peels (MP) waste and its subsequent effects on adsorption of cationic methylene blue (MB) from aqueous solution. AC was synthesized from MP waste under mild experimental conditions and was ball milled for a short time (30 min-120 min) at 350 rpm. The physicochemical properties of ball milled AC (BMAC) were investigated using BET, FTIR, TGA, FESEM, XRD and particle size distribution analysis. Various experimental results revealed that MB adsorption on BMAC was greatly influenced by basic pH, contact time and high temperature. The adsorption capability of BMAC was found to increase with decreasing particle size with ball milling. Kinetics study revealed that the adsorption capability of BMAC was best represented by pseudo second order kinetic model and adsorption equilibrium was well described by Langmuir isotherm. The adsorption process was endothermic and spontaneous as revealed by thermodynamic study. Overall, this work demonstrated that ball milling decreases the particle size of AC, increased its efficiency for adsorption of dye, and opened new ways for activation of AC using the ball-milling technique. (c) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页码：723 / 733
页数：11
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