N-Heterocyclic carbene-nitrogen molybdenum catalysts for utilization of CO2

被引：7
作者：
Chen, Fei [1 ]
Tao, Sheng [2 ]
Liu, Ning [2 ]
Dai, Bin [1 ,2 ]
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
[2] Shihezi Univ, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Sch Chem & Chem Engn, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China
来源：
POLYHEDRON | 2021年 / 196卷
关键词：
Mo catalysis; Carbon dioxide; Cycloaddition; Cyclic carbonate; Carboxylation; CARBON-DIOXIDE UTILIZATION; CYCLIC CARBONATES; BIFUNCTIONAL CATALYSTS; SUSTAINABLE CONVERSION; EFFICIENT CATALYSTS; IONIC LIQUIDS; EPOXIDES; COMPLEXES; POLYCARBONATES; FIXATION;
D O I：
10.1016/j.poly.2020.114990
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new N-heterocyclic carbene-nitrogen molybdenum complex was synthesized, and its catalytic activity was evaluated in the cycloaddition of epoxides with CO2. The molybdenum complex combined with tetrabutyl ammonium iodide (TBAI) resulted in a catalytic system for efficient conversion of a wide range of terminal and internal epoxides under 80 degrees C and 5-7 bar pressure for CO2. The cooperative catalysis mechanism between molybdenum complex and TBAI was elucidated, in which molybdenum complex was used as Lewis acid, and TBAI was employed as nucleophilic reagent. In addition, the NHC-Mo catalytic system was also successfully applied for the direct carboxylation of terminal alkynes with CO2. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数：9
相关论文
共 64 条
  • [51] Chiral Cobalt(III) Complexes as Bifunctional BrOnsted Acid-Lewis Base Catalysts for the Preparation of Cyclic Organic Carbonates
    Rulev, Yuri A.
    Larionov, Vladimir A.
    Lokutova, Anastasia V.
    Moskalenko, Margarita A.
    Lependina, Ol'ga L.
    Maleev, Victor I.
    North, Michael
    Belokon, Yuri N.
    [J]. CHEMSUSCHEM, 2016, 9 (02) : 216 - 222
  • [52] Transformation of carbon dioxide
    Sakakura, Toshiyasu
    Choi, Jun-Chul
    Yasuda, Hiroyuki
    [J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2365 - 2387
  • [53] Facile synthesis of cyclic carbonates from CO2 and epoxides with cobalt(II)/onium salt based catalysts
    Sibaouih, Ahlam
    Ryan, Paul
    Leskela, Markku
    Rieger, Bernhard
    Repo, Timo
    [J]. APPLIED CATALYSIS A-GENERAL, 2009, 365 (02) : 194 - 198
  • [54] New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2 into Cyclic Carbonates and Cross-Linked Polycarbonates
    Taherimehr, Masoumeh
    Cardoso Costa Serta, Joao Paulo
    Kleij, Arjan W.
    Whiteoak, Christopher J.
    Pescarmona, Paolo P.
    [J]. CHEMSUSCHEM, 2015, 8 (06) : 1034 - 1042
  • [55] Unexpected Macrocyclic Multinuclear Zinc and Nickel Complexes that Function as Multitasking Catalysts for CO2 Fixations
    Takaishi, Kazuto
    Nath, Bikash Dev
    Yamada, Yuya
    Kosugi, Hiroyasu
    Ema, Tadashi
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (29) : 9984 - 9988
  • [56] Cooperative catalyst system for the synthesis of oleochemical cyclic carbonates from CO2 and renewables
    Tenhumberg, Nils
    Buettner, Hendrik
    Schaeffner, Benjamin
    Kruse, Daniela
    Blumenstein, Michael
    Werner, Thomas
    [J]. GREEN CHEMISTRY, 2016, 18 (13) : 3775 - 3788
  • [57] Environmentally Benign CO2-Based Copolymers: Degradable Polycarbonates Derived from Dihydroxybutyric Acid and Their Platinum-Polymer Conjugates
    Tsai, Fu-Te
    Wang, Yanyan
    Darensbourg, Donald J.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (13) : 4626 - 4633
  • [58] Chemical fixation of carbon dioxide catalyzed via cobalt (III) ONO pincer ligated complexes
    Ullah, Habib
    Mousavi, Bibimaryam
    Younus, Hussein A.
    Khattak, Zafar A. K.
    Chaemchuen, Somboon
    Suleman, Suleman
    Verpoort, Francis
    [J]. COMMUNICATIONS CHEMISTRY, 2019, 2 (1)
  • [59] Selective C-N Bond-Forming Reaction of 2,6-Dibromopyridine with Amines
    Wang, Lei
    Liu, Ning
    Dai, Bin
    Hu, Hengcai
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (29) : 6493 - 6500
  • [60] An Efficient Iron Catalyst for the Synthesis of Five- and Six-Membered Organic Carbonates under Mild Conditions
    Whiteoak, Christopher J.
    Martin, Eddy
    Martinez Belmonte, Marta
    Benet-Buchholz, Jordi
    Kleij, Arjan W.
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2012, 354 (2-3) : 469 - 476
1234567