Fast and highly anisotropic thermal transport through vertically aligned carbon nanotube arrays

被引:151
作者
Ivanov, Ilia [1 ]
Puretzky, Alexander [1 ]
Eres, Gyula [1 ]
Wang, Hsin [1 ]
Pan, Zhengwei [1 ]
Cui, Hongtao [1 ]
Jin, Rongying [1 ]
Howe, Jane [1 ]
Geohegan, David B. [1 ]
机构
[1] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA
关键词
D O I
10.1063/1.2397008
中图分类号
O59 [应用物理学];
学科分类号
摘要
This letter reports on fast and highly anisotropic thermal transport through millimeter-tall, vertically aligned carbon nanotube arrays (VANTAs) synthesized by chemical vapor deposition on Si substrates. Thermal diffusivity measurements were performed for both longitudinal and transverse to the nanotube alignment direction, with longitudinal values as large as 2.1 +/- 0.2 cm(2)/s and anisotropy ratios as large as 72. Longitudinal thermal conductivities of 15.3 +/- 1.8 W/(m K) for porous 8 +/- 1 vol % VANTAs in air and 5.5 +/- 0.7 W/(m K) for epoxy-infiltrated VANTAs already exceed those of phase-changing thermal interface materials used in microelectronics. Data suggest that further improvements are possible through optimization of density and defects in the arrays.
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共 23 条
[1]   Unusually high thermal conductivity of carbon nanotubes [J].
Berber, S ;
Kwon, YK ;
Tománek, D .
PHYSICAL REVIEW LETTERS, 2000, 84 (20) :4613-4616
[2]   Super-compressible foamlike carbon nanotube films [J].
Cao, AY ;
Dickrell, PL ;
Sawyer, WG ;
Ghasemi-Nejhad, MN ;
Ajayan, PM .
SCIENCE, 2005, 310 (5752) :1307-1310
[3]   In situ control of the catalyst efficiency in chemical vapor deposition of vertically aligned carbon nanotubes on predeposited metal catalyst films [J].
Eres, G ;
Puretzky, AA ;
Geohegan, DB ;
Cui, H .
APPLIED PHYSICS LETTERS, 2004, 84 (10) :1759-1761
[4]   Interpretation of Raman spectra of disordered and amorphous carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107
[5]   Magnetically aligned single wall carbon nanotube films: Preferred orientation and anisotropic transport properties [J].
Fischer, JE ;
Zhou, W ;
Vavro, J ;
Llaguno, MC ;
Guthy, C ;
Haggenmueller, R ;
Casavant, MJ ;
Walters, DE ;
Smalley, RE .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (04) :2157-2163
[6]   Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes [J].
Hata, K ;
Futaba, DN ;
Mizuno, K ;
Namai, T ;
Yumura, M ;
Iijima, S .
SCIENCE, 2004, 306 (5700) :1362-1364
[7]   THERMAL-CONDUCTIVITY AND RAMAN-SPECTRA OF CARBON-FIBERS [J].
HEREMANS, J ;
RAHIM, I ;
DRESSELHAUS, MS .
PHYSICAL REVIEW B, 1985, 32 (10) :6742-6747
[8]   Quantized phonon spectrum of single-wall carbon nanotubes [J].
Hone, J ;
Batlogg, B ;
Benes, Z ;
Johnson, AT ;
Fischer, JE .
SCIENCE, 2000, 289 (5485) :1730-1733
[9]   Electrical and thermal transport properties of magnetically aligned single walt carbon nanotube films [J].
Hone, J ;
Llaguno, MC ;
Nemes, NM ;
Johnson, AT ;
Fischer, JE ;
Walters, DA ;
Casavant, MJ ;
Schmidt, J ;
Smalley, RE .
APPLIED PHYSICS LETTERS, 2000, 77 (05) :666-668
[10]   Aligned carbon nanotube composite films for thermal management [J].
Huang, H ;
Liu, CH ;
Wu, Y ;
Fan, SS .
ADVANCED MATERIALS, 2005, 17 (13) :1652-+