A Metallo-molecular Cage That Can Close the Apertures with Coordination Bonds

被引：64

作者：

Akine, Shigehisa ^{[1
]}

Miyashita, Masato ^{[2
]}

Nabeshima, Tatsuya ^{[2
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan

[2] Univ Tsukuba, Fac Pure & Appl Sci, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058571, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2017年 / 139卷 / 13期

关键词：

HEMICARCERAND; RECOGNITION; COMPLEXES; METALLOCRYPTAND; ENCAPSULATION; DISCRETE; SYMMETRY; EXCHANGE; DESIGN; LIGAND;

D O I：

10.1021/jacs.7b00840

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We designed a novel tricobalt(III) metallomolecular cage in which its apertures can be closed with bifunctional ligands via coordination bonds. A closed-cage complex was easily formed by ligand exchange of its open cage analogue. Guest uptake/release by the open-cage complex was sufficiently fast to quickly reach guest-binding equilibrium, while that by the closed-cage complex was extremely slow and took about 1 week to reach equilibrium. The guest uptake was retarded by at least 2000 times by introduction of the bifunctional ligands at the cage apertures.

引用

页码：4631 / 4634

页数：4

共 69 条

[31] Engineering Organic Macrocycles and Cages: Versatile Bonding Approaches [J].

Huang, Sheng-Li ;

Jin, Guo-Xin ;

Luo, He-Kuan ;

Hor, T. S. Andy .

CHEMISTRY-AN ASIAN JOURNAL, 2015, 10 (01) :24-42

[32]

Inokuma Y, 2011, NAT CHEM, V3, P349, DOI [10.1038/NCHEM.1031, 10.1038/nchem.1031]

[33] Carceplexes and hemicarceplexes [J].

Jasat, A ;

Sherman, JC .

CHEMICAL REVIEWS, 1999, 99 (04) :931-967

[34] Reactivity within a confined self-assembled nanospace [J].

Koblenz, Tehila S. ;

Wassenaar, Jeroen ;

Reek, Joost N. H. .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (02) :247-262

[35] Building on Cram's Legacy: Stimulated Gating in Hemicarcerands [J].

Liu, Fang ;

Helgeson, Roger C. ;

Houk, K. N. .

ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (07) :2168-2176

[36] Gating in Host-guest Chemistry [J].

Liu, Fang ;

Wang, Hao ;

Houk, Kendall N. .

CURRENT ORGANIC CHEMISTRY, 2013, 17 (14) :1470-1480

[37] Gated container molecules [J].

Liu Fang ;

Wang Hao ;

Houk, K. N. .

SCIENCE CHINA-CHEMISTRY, 2011, 54 (12) :2038-2044

[38]

MacGillivray LR, 1999, ANGEW CHEM INT EDIT, V38, P1019, DOI 10.1002/(SICI)1521-3773(19990419)38:8<1018::AID-ANIE1018>3.0.CO

[39]

2-G

[40] Shape-Persistent Organic Cage Compounds by Dynamic Covalent Bond Formation [J].

Mastalerz, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (30) :5042-5053

← 1 2 3 4 5 6 7 →