A Metallo-molecular Cage That Can Close the Apertures with Coordination Bonds

被引：63

作者：

Akine, Shigehisa ^{[1
]}

Miyashita, Masato ^{[2
]}

Nabeshima, Tatsuya ^{[2
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan

[2] Univ Tsukuba, Fac Pure & Appl Sci, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058571, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2017年 / 139卷 / 13期

关键词：

HEMICARCERAND; RECOGNITION; COMPLEXES; METALLOCRYPTAND; ENCAPSULATION; DISCRETE; SYMMETRY; EXCHANGE; DESIGN; LIGAND;

D O I：

10.1021/jacs.7b00840

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We designed a novel tricobalt(III) metallomolecular cage in which its apertures can be closed with bifunctional ligands via coordination bonds. A closed-cage complex was easily formed by ligand exchange of its open cage analogue. Guest uptake/release by the open-cage complex was sufficiently fast to quickly reach guest-binding equilibrium, while that by the closed-cage complex was extremely slow and took about 1 week to reach equilibrium. The guest uptake was retarded by at least 2000 times by introduction of the bifunctional ligands at the cage apertures.

引用

页码：4631 / 4634

页数：4

共 69 条

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