Cluster compounds [Ca(DMF)6][Mo6Cl14] and [{Ca(OPPh3)4}{Mo6Cl14}]∞:: Synthesis, crystal structure, and properties

被引：14

作者：

Kozhomuratova, Zh. S. ^{[1
]}

Mironov, Yu. V. ^{[1
]}

Shestopalov, M. A. ^{[1
]}

Gaifulin, Ya. M. ^{[1
]}

Kurat'eva, N. V. ^{[1
]}

Uskov, E. M. ^{[1
]}

Fedorov, V. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 33卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S1070328407010010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [Ca(DMF)(6)][Mo6Cl14] Complex (I) was synthesized by reacting octahedral cluster Mo complex (H3O)(2)Mo6Cl14 center dot 6H(2)O with the Ca2+ cation in DME Analogous reaction carried out in the presence of triphenylphosphine oxide Ph3PO in acetonitrile resulted in [{Ca(OPPh3)(4)} {Mo6Cl14}] (11). According to X-ray diffraction data, complex I has ionic structure, while the structure of complex 11 consists of infinite linear chains of the cluster anionic complexes {Mo6Cl14}(2-) bonded to the cationic Ca complexes [Ca(OPPH3)(4)}(2+). Both complexes exhibit intensive luminescence in red and near-IR regions of the spectrum.

引用

页码：1 / 6

页数：6

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