Effect of Formulation and Pressure on Injection Moulded Soy Protein-Based Plastics

被引:7
作者
Alvarez-Castillo, Estefania [1 ]
Caballero, Gabriel [2 ]
Guerrero, Antonio [1 ]
Bengoechea, Carlos [1 ]
机构
[1] Univ Seville, Escuela Politecn Super, Dept Ingn Quim, Calle Virgen Africa 7, Seville 41011, Spain
[2] Univ Seville, Fac Quim, Dept Ingn Quim, Calle Prof Garcia Gonzalez 1, Seville 41012, Spain
关键词
Soy protein; Rheology; Injection moulding; Viscoelasticity; Processing; Absorbent;
D O I
10.1007/s10924-021-02082-w
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The replacement of plastic materials derived from petroleum derivatives by highly biodegradable materials has been pursued to counteract the global environmental damage caused by their accumulated landfilling. In this sense, the feasibility of a soy protein isolate (SPI) to obtain processed materials has been extensively documented. In the present study, the characterization of injection moulded soy protein-based materials with different SPI/glycerol ratios (50/50, 55/45 and 60/40) has been carried out for different processing conditions of pressure (250, 500, 1000 bar) and temperature (80, 100, 120 degrees C). This characterization was performed in terms of their viscoelastic and tensile properties, water uptake capacity and soluble mater loss. An increase on the mechanical and viscoelastic properties was denoted when the protein content was higher, which could be related to an enhancement of interactions due to a greater proximity between chains. Similar effects were observed when the injection pressure was increased, eventually achieving a remarkable elongation at break value of 2, 7500% when processed at 1000 bar. Moreover, mould temperature was detected to be the most influential parameter on their water uptake capacity, resulting in a hindering of these parameter as higher temperatures were used. The effect of pressure on water uptake of these materials was opposite and milder to that found for temperature.
引用
收藏
页码:2789 / 2796
页数:8
相关论文
共 45 条
[1]   Recent Advances in Edible Polymer Based Hydrogels as a Sustainable Alternative to Conventional Polymers [J].
Ali, Akbar ;
Ahmed, Shakeel .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2018, 66 (27) :6940-6967
[2]  
Alvarez-Castillo E, 2019, AFINIDAD, V76, P23
[3]   Effect of pH on the properties of porcine plasma-based superabsorbent materials [J].
Alvarez-Castillo, Estefania ;
Bengoechea, Carlos ;
Guerrero, Antonio .
POLYMER TESTING, 2020, 85
[4]   Composites from by-products of the food industry for the development of superabsorbent biomaterials [J].
Alvarez-Castillo, Estefania ;
Bengoechea, Carlos ;
Guerrero, Antonio .
FOOD AND BIOPRODUCTS PROCESSING, 2020, 119 :296-305
[5]   Development of green superabsorbent materials from a by-product of the meat industry [J].
Alvarez-Castillo, Estefania ;
Bengoechea, Carlos ;
Rodriguez, Natalia ;
Guerrero, Antonio .
JOURNAL OF CLEANER PRODUCTION, 2019, 223 :651-661
[6]   Optimization of a thermal process for the production of superabsorbent materials based on a soy protein isolate [J].
Alvarez-Castillo, Estefania ;
Del Toro, Alejandro ;
Manuel Aguilar, Jose ;
Guerrero, Antonio ;
Bengoechea, Carlos .
INDUSTRIAL CROPS AND PRODUCTS, 2018, 125 :573-581
[7]   Cellulose-based hydrogels for personal care products [J].
Bashari, Azadeh ;
Shirvan, Anahita Rouhani ;
Shakeri, Mina .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2018, 29 (12) :2853-2867
[8]   Overview of the potential of microalgae for CO2 sequestration [J].
Bhola, V. ;
Swalaha, F. ;
Kumar, R. Ranjith ;
Singh, M. ;
Bux, F. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2014, 11 (07) :2103-2118
[9]   Advances in the Use of Protein-Based Materials: Toward Sustainable Naturally Sourced Absorbent Materials [J].
Capezza, A. J. ;
Newson, W. R. ;
Olsson, R. T. ;
Hedenqvist, M. S. ;
Johansson, E. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (05) :4532-4547
[10]   Novel Sustainable Superabsorbents: A One-Pot Method for Functionalization of Side-Stream Potato Proteins [J].
Capezza, Antonio J. ;
Glad, David ;
Ozeren, Husamettin Deniz ;
Newson, William R. ;
Olsson, Richard T. ;
Johansson, Eva ;
Hedenqvist, Mikael S. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (21) :17845-17854