Controlling molecular weight and polymer architecture during the Passerini three component step-growth polymerization

被引：37

作者：

Oelmann, S. ^{[1
]}

Solleder, S. C. ^{[1
]}

Meier, M. A. R. ^{[1
]}

机构：

[1] KIT, IOC, Fritz Haber Weg 6, D-76131 Karlsruhe, Germany

来源：

POLYMER CHEMISTRY | 2016年 / 7卷 / 10期

关键词：

D O I：

10.1039/c5py02030a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new approach to control the molecular weight and polymer architecture using the Passerini three-component step-growth polymerization is described. Starting from an AB-type monomer, linear homopolymers, diblock copolymers, as well as star-shaped polymers were synthesized in an efficient manner. By varying the ratio of the AB-type monomer and a suitable irreversible chain transfer agent (ICTA), different polymer architectures with specific molecular weights and high end-group fidelity were obtained.

引用

页码：1857 / 1860

页数：4

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