Reactions of silicon atoms with benzene: A matrix-spectroscopic study

被引：6
|
作者：
Maier, G [1 ]
Reisenauer, HP [1 ]
机构：
[1] Univ Giessen, Inst Organ Chem, D-35392 Giessen, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 03期
关键词：
matrix isolation; photochemistry; isomerizations; silicon; density functional calculations;
D O I：
10.1002/ejoc.200390083
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of silicon atoms with benzene in argon at 10 K has been studied. The addition to the aromatic pi-system of benzene occurs in a [1,4]-fashion. Upon irradiation the pi-adduct 7-silabicyclo[2.2.1]heptadien-7-ylidene (2) rearranges to the formal C-C insertion product 1-silacycloheptatrienylidene (3). The structural elucidation of the new species is based on comparison of the experimental observations with density functional calculations.
引用
收藏
页码：488 / 491
页数：4
相关论文
共 50 条
  • [31] Reactions of Fluorine Atoms with Benzene, Fluorobenzene, and Chlorobenzene
    Vasiliev, E. S.
    Morozov, I. I.
    Volkov, N. D.
    Savilov, S. V.
    Morozova, O. S.
    Butkovskaya, N. I.
    Khomyakova, P. S.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2024, 18 (05) : 1309 - 1319
  • [32] Shock-Tube Study of the Reactions of Hydrogen Atoms with Benzene and Phenyl Radicals
    Giri, Binod R.
    Bentz, Tobias
    Hippler, Horst
    Olzmann, Matthias
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2009, 223 (4-5): : 539 - 549
  • [33] Hetero π systems.: 28 -: Reaction of silicon atoms with acetylene and ethylene:: Generation and matrix-spectroscopic identification of C2H2Si and C2H4Si isomers
    Maier, G
    Reisenauer, HP
    Egenolf, H
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1998, 1998 (07) : 1313 - 1317
  • [34] Matrix isolation infrared spectroscopic and density functional theoretical studies of the reactions of scandium atoms with methanol
    Chen, MH
    Huang, ZG
    Zhou, MF
    JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (28): : 5950 - 5955
  • [35] Matrix Isolation Infrared Spectroscopic and Density Functional Theoretical Studies on the Reactions of Lanthanum Atoms with Acetylene
    Teng, Yun-Lei
    Xu, Qiang
    JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (41): : 10274 - 10279
  • [36] Matrix isolation FTIR spectroscopic and density functional theoretical studies of the reactions of magnesium atoms with methanol
    Huang, ZG
    Chen, MH
    Liu, QN
    Zhou, MF
    JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (51): : 11380 - 11385
  • [37] MATRIX-ISOLATION-INFRARED AND LASER RAMAN-SPECTROSCOPIC STUDY OF THE GAS-PHASE REACTIONS OF CHLORINE ATOMS AND OZONE
    BHATIA, SC
    HALL, JH
    JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (14): : 2055 - 2060
  • [38] Reactions of Recoil 11C Atoms with Benzene
    Radiochim Acta, 1-2 (45):
  • [39] Reaktion von atomarem Silicium mit Methanol: Matrixspektroskopische Identifizierung von Methoxysilylen [1]Reaction of Atomic Silicon with Methanol: Matrix-Spectroscopic Identification of Methoxysilylene
    Günther Maier
    Hans P. Reisenauer
    Heiko Egenolf
    Monatshefte für Chemie / Chemical Monthly, 1999, 130 (1) : 227 - 235
  • [40] Reactions of recoil C-11 atoms with benzene
    Kuipers, P
    Leurs, GAJ
    Lindner, L
    Brinkman, GA
    RADIOCHIMICA ACTA, 1997, 77 (1-2) : 45 - 58
12345