Phase Transformations of Gelling Substances in Irradiated Aqueous Solutions

被引：1

作者：

Kholodkova, E. M. ^{[1
]}

Kasterin, A. I. ^{[1
]}

Ponomarev, A. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia

来源：

HIGH ENERGY CHEMISTRY | 2019年 / 53卷 / 04期

关键词：

radiolysis; aqueous suspension; gelling agent; aggregation; sedimentation; ELECTRON-BEAM; RADIATION; DISPERSIONS; HYDROGEL; WATER;

D O I：

10.1134/S0018143919040064

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pectin, starch, gelatin, and wheat flour in dilute aqueous solutions undergo irreversible aggregation and sedimentation even at absorbed doses lower than 1 kGy. Irradiation narrows the size distribution of suspended particles in solution. It is noted that the effect of irradiation is caused not only by intermolecular crosslinking but also by the electrostatic effect of charged radiolytic intermediates. The decrease in the aggregative stability of gelling substances on the irradiation of their dilute solutions can be used for practical wastewater treatment and for the target-oriented synthesis of aggregates with a specified particle size distribution.

引用

页码：309 / 313

页数：5

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