Synthesis and optical properties of water-soluble diketopyrrolopyrroles

被引：10

作者：

Grzybowski, Marek ^{[1
]}

Glodkowska-Mrowka, Eliza ^{[2
]}

Clermont, Guillame ^{[3
]}

Blanchard-Desce, Mireille ^{[3
]}

Gryko, Daniel T. ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland

[2] Med Univ Warsaw, Dept Lab Diagnost & Clin Immunol Dev Age, Marszakowska 24, PL-00576 Warsaw, Poland

[3] Univ Bordeaux, Inst Mol Sci, CNRS, UMR 5255, A12 Batiment,351 Cours Liberat, F-33405 Talence, France

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2017年 / 53卷 / 01期

关键词：

diketopyrrolopyrroles; dyes; quaternary ammonium salts; fluorescence; two-photon absorption; EXCITATION CROSS-SECTIONS; THIN-FILM TRANSISTORS; 2-PHOTON ABSORPTION; CONJUGATED POLYMERS; FLUORESCENT; FLUOROPHORES; PROBES; DYES; EFFICIENT; PIGMENTS;

D O I：

10.1007/s10593-017-2023-y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two diketopyrrolopyrroles containing electron-rich 3,4-dimethoxyphenyl and 2-furyl aromatic groups were decorated with N-alkyl substituents containing quaternary ammonium moieties. The obtained dyes were readily soluble in water, showed an intense visible absorption with relatively high two-photon absorption cross-sections and some of them could stain eukaryotic cells. A dye containing two tetraalkylammonium moieties in its side chains showed high fluorescence quantum yield (> 50%) both in water and in acetonitrile, whereas the fluorescence of pyridinium salt was significantly quenched. The two-photon absorption peaks were located at similar to 720 nm.

引用

页码：72 / 77

页数：6

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