Anion-directed assembly in the formation of a new mixed-ligand metal organic framework

被引：3

作者：

Bai, Shuqiong ^{[1
]}

Fu, Zhiyong ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 15期

基金：

美国国家科学基金会;

关键词：

Anion templation; Metal organic framework; Mixed-ligand; Molecular structure; TEMPLATED SYNTHESIS; COORDINATION; POLYMER; RECOGNITION; TOPOLOGY; CLUSTERS; NETWORK; COMPLEX; SERIES; UNITS;

D O I：

10.1016/j.ica.2009.09.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new two-dimensional metal organic framework is synthesized and characterized. The encapsulated chloride anions organize a collection of building units into a novel mixed-ligand metal organic supramolecular assembly, indicating specific host-guest recognition. By contrast, the addition of F-, Br-, I-, PO43- anions only give out the coordination complexes with single ligand. Reactions of the Zn2+ ion with 1,2,4-benzenetricarboxylic acid and pyridine-2,5-dicarboxylic acid have been investigated with emphasis on the factors that govern reaction results. And the sample is characterized by the elemental analysis, TGA, XPRD, IR, and luminescent data. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：5163 / 5169

页数：7

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