Copper-Mediated Sulfonylation of Aryl C(sp2)-H Bonds with Sodium and Lithium Sulfinates

被引：48
作者：
Liang, Shuai [1 ]
Liu, Nai-Wei [1 ]
Manolikakes, Georg [1 ]
机构：
[1] Goethe Univ Frankfurt, Dept Organ Chem & Chem Biol, Max von Laue Str 7, D-60438 Frankfurt, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2016年 / 358卷 / 01期
关键词：
amide-oxazolines; C-H activation; copper; sulfinates; sulfonylation; UNSYMMETRICAL DIARYL SULFONES; C-H BONDS; ACID SALTS; FUNCTIONALIZATION; HALIDES; ARENES; MECHANISM; INDOLES; ACCESS;
D O I：
10.1002/adsc.201500793
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A copper-mediated direct sulfonylation of aryl C(sp(2))-H bonds with sodium and lithium sulfinates is reported. Various aryl sulfones were synthesized in moderate to excellent yields with good functional group tolerance.
引用
收藏
页码：159 / 163
页数：5
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