Nucleophilic Addition of Aromatic Amide Oximes to [2-B10H9NCC2H5]- Anion

被引：9

作者：

Bolotin, D. S. ^{[1
]}

Demakova, M. Ya. ^{[1
]}

Daines, E. A. ^{[1
]}

Avdontseva, M. S. ^{[1
]}

Zhdanov, A. P. ^{[2
]}

Zhizhin, K. Yu. ^{[2
]}

Kuznetsov, N. T. ^{[2
]}

机构：

[1] St Petersburg State Univ, Univ Skaya Nab 7-9, St Petersburg 199034, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

closo-decaborate anion; nitrilium derivatives; nucleophilic addition; amide oximes; oximes; CLOSO-DECABORATE CLUSTERS; COORDINATION CHEMISTRY; NITRILIUM DERIVATIVES; CYCLOADDITION; REACTIVITY;

D O I：

10.1134/S107036321701008X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of closo-decaborate anions containing an O-iminoacylamide oxime fragment were synthesized by nucleophilic addition of aromatic amide oximes to 2-propionitrilium closo-decaborate anion. The isolated compounds were characterized by IR, H-1, C-13-{H-1}, and B-11-{H-1} NMR, and mass spectra. The structure of ((PhP)-P-4)[2-B10H9NH= C(Et) ON= C(NH2)C6H4Me-2] was determined by single-crystal X-ray analysis.

引用

页码：37 / 43

页数：7

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