Synthesis of MoO3 nanostructures and their facile conversion to MoS2 fullerenes and nanotubes

被引：66
作者：
Therese, Helen A.
Zink, Nicole
Kolb, Ute
Tremel, Wolfgang
机构：
[1] Johannes Gutenberg Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany
[2] Johannes Gutenberg Univ Mainz, Inst Chem Phys, D-55099 Mainz, Germany
来源：
SOLID STATE SCIENCES | 2006年 / 8卷 / 10期
关键词：
MoO3; nanorods; thermolysis; MoS2; nanotubes; inorganic fullerene-like;
D O I：
10.1016/j.solidstatesciences.2006.05.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The fast thermolysis of ammonium molybdate leads to a mixture Of MoO3 and Mo5.3O14.5(OH)(2.8)(H2O)(1,36) with spherical and rod-like morphologies. The oxide mixture can be converted in quantitative yield to inorganic fullerene-type (IF) MoS2 and MoS2 nanotubes (NT) by H2S reduction using a facile and quick procedure. The products were studied by X-Ray Diffraction (XRD) and by Transmission Electron Microscopy (TEM). TEM analysis reveals that the spherical and rod-like morphology of the oxide precursor is preserved during the H2S treatment. (c) 2006 Elsevier Masson SAS. All rights reserved.
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收藏
页码：1133 / 1137
页数：5
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