Phthalimide-N-sulfenyl chloride in the Ti-catalyzed asymmetric sulfenylation of β-keto esters

被引：28

作者：

Srisailam, Shravan K. ^{[1
]}

Togni, Antonio ^{[1
]}

机构：

[1] ETH, Swiss Fed Inst Technol, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 18期

关键词：

D O I：

10.1016/j.tetasy.2006.10.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enantioselective sulfenylation of beta-keto esters was carried out using phthalimide-N-sulfenyl chloride in the presence of a Ti(TADDOLato) catalyst affording up to 60% ee. X-ray crystal structures of product compounds 3a and 9a were determined. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：2603 / 2607

页数：5

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