Phthalimide-N-sulfenyl chloride in the Ti-catalyzed asymmetric sulfenylation of β-keto esters

被引：28
|
作者：
Srisailam, Shravan K. [1 ]
Togni, Antonio [1 ]
机构：
[1] ETH, Swiss Fed Inst Technol, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland
来源：
TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 18期
关键词：
D O I：
10.1016/j.tetasy.2006.10.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The enantioselective sulfenylation of beta-keto esters was carried out using phthalimide-N-sulfenyl chloride in the presence of a Ti(TADDOLato) catalyst affording up to 60% ee. X-ray crystal structures of product compounds 3a and 9a were determined. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2603 / 2607
页数：5
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