Adenine-containing block copolymers via ring-opening metathesis polymerization: Synthesis and self-assembly into rod morphologies

被引：94

作者：

Bazzi, HS ^{[1
]}

Sleiman, HF ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

MACROMOLECULES | 2002年 / 35卷 / 26期

关键词：

D O I：

10.1021/ma025676o

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The first synthesis of adenine-containing polymers and block copolymers using the ring-opening metathesis polymerization of non-covalently protected monomers are shown. Studies of the copolymer 9 reveal an unexpected cylindrical morphology, which can be interpreted as arising from the hydrogen-bonding self-complementarity of the adenine units in the micellar core. Thus, further studies are currently conducted to fully characterize this morphogenesis mechanism as well as to study the effect of hydrogen-bonding guests on the polymer morphologies.

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页码：9617 / 9620

页数：4

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