Three 9,19-cyclotetracyclic triterpenes from Skimmia wallichii

被引:13
作者
Kostova, I
Simeonov, M
Iossifova, T
Tappe, R
Pardeshi, N
Budzikiewicz, H
机构
[1] UNIV COLOGNE,INST ORGAN CHEM,D-50939 COLOGNE,GERMANY
[2] BULGARIAN ACAD SCI,INST ORGAN CHEM,CTR PHYTOCHEM,BU-1113 SOFIA,BULGARIA
[3] UNIV DELHI,DEPT CHEM,DELHI 110007,INDIA
关键词
Skimmia wallichii; Rutaceae; 9,19-cyclotetracyclic triterpenes; skimmiwallichin; skimmiwallinin; skimmiwallin;
D O I
10.1016/0031-9422(96)00320-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Phytochemical studies on Skimmia wallichii resulted in the isolation of skimmiwallichin, skimmiwallin and a new cycloartanol type compound skimmiwallinin. The structure of skimmiwallinin is elucidated as 3 beta-methoxy-24-methyl-24-ethyl-9,19-cyclolanost-25(26)-ene on the basis of spectral studies. The structures of skimmiwallichin and another tetracyclic triterpene, now named skimmiwallin, were revised and established to be 3 beta-methoxy-24,24-diethyl-9,19-cyclolanost-25(26)-ene and 3 beta-methoxy-25-ethyl-9,19-cyclolanost-24(24')-ene, respectively. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:643 / 648
页数:6
相关论文
共 8 条
[1]   APPLICATION OF MASS SPECTROMETRY TO STRUCTURAL INVESTIGATION OF 9,19-CYCLOSTEROLS AND TRITERPENES [J].
APLIN, RT ;
HORNBY, GM .
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (11) :1078-&
[2]  
AUDIER HE, 1966, TETRAHEDRON LETT, P4341
[3]   RECENT ADVANCES IN MASS-SPECTROMETRY OF STEROIDS [J].
DJERASSI, C .
PURE AND APPLIED CHEMISTRY, 1978, 50 (03) :171-184
[4]  
KOSTOVA I, 1989, 5 INT C CHEM BIOT BI, V2, P110
[5]  
KOSTOVA IN, 1977, INDIAN J CHEM B, V15, P811
[6]   A STEROIDAL ESTER FROM COELOGYNE-UNIFLORA [J].
MAJUMDER, PL ;
PAL, S .
PHYTOCHEMISTRY, 1990, 29 (08) :2717-2720
[7]   THE CONFORMATION OF CYCLOARTENOL INVESTIGATED BY NMR AND MOLECULAR MECHANICS [J].
MILON, A ;
NAKATANI, Y ;
KINTZINGER, JP ;
OURISSON, G .
HELVETICA CHIMICA ACTA, 1989, 72 (01) :1-&
[8]   MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .146. MASS SPECTROMETRIC FRAGMENTATIONS TYPICAL OF STEROLS WITH UNSATURATED SIDE CHAINS [J].
WYLLIE, SG ;
DJERASSI, C .
JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (01) :305-&