Facile synthesis of ultrathin NiCo2S4 nano-petals inspired by blooming buds for high-performance supercapacitors

被引:276
作者
Wen, Yuxiang [1 ]
Peng, Shanglong [1 ]
Wang, Zilei [1 ]
Hao, Jiaxin [1 ]
Qin, Tianfeng [1 ]
Lu, Shuqi [1 ]
Zhang, Jiachi [1 ]
He, Deyan [1 ]
Fan, Xiaoyan [3 ]
Cao, Guozhong [2 ]
机构
[1] Lanzhou Univ, Sch Phys Sci & Technol, Minist Educ, Key Lab Magnetism & Magnet Mat, Lanzhou 730000, Peoples R China
[2] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[3] Qingdao Univ Sci & Technol, Coll Math & Phys, Qingdao 266061, Peoples R China
基金
中国国家自然科学基金;
关键词
NICKEL-COBALT SULFIDE; IN-SITU GROWTH; HIGH-ENERGY DENSITY; NANOSHEET ARRAYS; NI FOAM; ASYMMETRIC SUPERCAPACITORS; ELECTRODE MATERIALS; HOLLOW SPHERES; NANOSTRUCTURES; EFFICIENT;
D O I
10.1039/c7ta01326d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
3D petal-like NiCo2S4 nanostructures have been fabricated via a simple, mild and efficient hydrothermal strategy and the growth mechanism of NiCo2S4 nano-petals has been investigated. Such NiCo2S4 nano-petal electrodes can deliver an ultrahigh specific capacitance of 2036.5 F g(-1) at a current density of 1 A g(-1), superior rate capability and remarkable cycle stability (94.3% of capacitance retention after 5000 cycles). The as-fabricated asymmetric supercapacitors based on NiCo2S4 nano-petals//active carbon electrodes demonstrate a high energy density of 35.6 W h kg(-1) at a power density of 819.5 W kg(-1), with both long-term cycling and high rate stabilities. Such supercapacitors have been tested to power ten LEDs (2.03 V, 20 mA) in series for around 60 minutes, indicating their great potential for practical application.
引用
收藏
页码:7144 / 7152
页数:9
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