Syndiospecific Styrene Polymerization in Aliphatic Solvents Catalyzed by FluTi(OiPr)3/MAO: Study of Polymerization Conditions

被引：0

作者：

Lugo, Luis E. ^{[1
,2
]}

Charles, Rogelio ^{[1
]}

Perez, Odilia ^{[2
]}

Cadenas, Gregorio ^{[2
]}

Revilla, Javier ^{[1
]}

机构：

[1] Ctr Invest & Desarrollo Tecnol, Lerma 52000, Mexico

[2] CIQA, Saltillo 25100, Coahuila, Mexico

来源：

MACROMOLECULAR SYMPOSIA | 2009年 / 283-84卷

关键词：

high-throughput screening; organometallic catalysts; polymerization; polystyrene; syndiotactic; TITANIUM METHYLALUMINOXANE CATALYST; SYNDIOTACTIC POLYSTYRENE; COPOLYMERS; COMPLEXES; MECHANISM;

D O I：

10.1002/masy.200950910

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Syndiotactic polymerization of styrene in aliphatic solvents (hexane and cyclohexane) and aliphatic solvent/toluene mixtures was evaluated using a previously reported catalytic system formed by FluTi((OPr)-Pr-i)(3)/MAO in order to evaluate polymerization reaction conditions and their effect on polymer tacticity. Highly syndiotactic polystyrene was produced indistinctly using pure aliphatic solvent or mixtures with toluene. on the other hand, the effect of polymerization conditions such as temperature, catalyst precursor and styrene concentrations, Al/Ti ratio and aliphatic solvent/toluene ratio over catalytic activity were analyzed.

引用

页码：67 / 77

页数：11

共 29 条

[1] A new approach to styrenic thermoplastic elastomers: Synthesis and characterization of crystalline styrene-butadiene-styrene triblock copolymers
Ban, HT
Kase, T
Kawabe, M
Miyazawa, A
Ishihara, T
Hagihara, H
Tsunogae, Y
Murata, M
Shiono, T
[J]. MACROMOLECULES, 2006, 39 (01) : 171 - 176
[2] Stereospecific sequential block copolymerizations of styrene and 1,3-butadiene with a C5Me5TiMe3/B(C6F5)3/Al(oct)3 catalyst
Ban, HT
Tsunogae, Y
Shiono, T
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (06) : 1188 - 1195
[3] Synthesis and characterization of cis-polybutadiene-block-syn-polystyrene copolymers with a cyclopentadienyl titanium trichloride/modified methylaluminoxane catalyst
Ban, HT
Tsunogae, Y
Shiono, T
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (11) : 2698 - 2704
[4] Syndiospecific polymerization of styrene with Cp*TiCl((OCH(R)CH2)2NAr)/MMAO
Chen, J
Zheng, ZJ
Pan, L
Pan, D
Li, YS
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (08) : 1562 - 1568
[5] SYNDIOSPECIFIC POLYMERIZATION OF STYRENE .1. TETRABENZYL TITANIUM METHYLALUMINOXANE CATALYST
CHIEN, JCW
SALAJKA, Z
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (09) : 1243 - 1251
[6] SYNDIOSPECIFIC POLYMERIZATION OF STYRENE .2. MONOCYCLOPENTADIENYLTRIBUTOXY TITANIUM METHYLALUMINOXANE CATALYST
CHIEN, JCW
SALAJKA, Z
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (09) : 1253 - 1263
[7] SYNDIOSPECIFIC POLYMERIZATION OF STYRENE .3. CATALYST STRUCTURE
CHIEN, JCW
SALAJKA, Z
DONG, S
[J]. MACROMOLECULES, 1992, 25 (12) : 3199 - 3203
[8] Kinetics of slurry phase polymerization of styrene to syndiotactic polystyrene with pentamethyl cyclopentadienyl titanium trimethoxide and methyl aluminoxane. I. Reaction rate analysis
Choi, KY
Chung, JS
Woo, BG
Hong, MH
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (08) : 2132 - 2137
[9] Syndiospecific polymerization of styrene using a heterogeneous titanocene catalyst
Entezami, A.
Agaalipour, M.
Moghaddam, P. Najafi
[J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2005, 2 (02) : 149 - 154
[10] Syndiospecific styrene polymerization with CpTiCl3/MAO:: Effects of the order of reactant addition on polymerization and polymer properties
Huang, B
Cao, K
Li, BG
Zhu, SP
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 94 (04) : 1449 - 1455

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