K2SrP4O12: a deep-UV transparent cyclophosphate as a nonlinear optical crystal

被引：68

作者：

Bai, Zhiyong ^{[1
,2
]}

Liu, Lehui ^{[1
]}

Zhang, Lizhen ^{[1
]}

Huang, Yisheng ^{[1
]}

Yuan, Feifei ^{[1
]}

Lin, Zhoubin ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 58期

关键词：

ALKALINE BERYLLIUM BORATE; RB; POLYPHOSPHATE; ENHANCEMENT; PHOSPHATES; CL;

D O I：

10.1039/c9cc04192c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benefiting from high transmittance of PO4 tetrahedra in the deep-ultraviolet (deep-UV) region, phosphates have been investigated as deep-UV nonlinear optical (NLO) candidates for years. So far, reported deep-UV NLO phosphates are orthophosphates and polyphosphates while cyclophosphates, important members of the phosphates family, have usually been neglected for use as deep-UV NLO crystals. Here, we first report a novel cyclotetraphosphate K2SrP4O12 (KSPO) as a deep-UV transparent NLO crystal. In its structure, the fundamental building groups are ring [P4O12](4-) groups. KSPO exhibits a moderate second-harmonic generation (SHG) response that is 0.5 times that of KH2PO4 (KDP) and a short deep-ultraviolet absorption edge smaller than 200 nm.

引用

收藏

页码：8454 / 8457

页数：4

相关论文

共 44 条

[1] KPb2(PO3)5: a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge [J].

Abudoureheman, Maierhaba ;

Han, Shujuan ;

Lei, Bing-Hua ;

Yang, Zhihua ;

Long, Xifa ;

Pan, Shilie .

JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (45) :10630-10637

[2] DESIGN AND SYNTHESIS OF AN ULTRAVIOLET-TRANSPARENT NONLINEAR-OPTICAL CRYSTAL SR2BE2B2O7 [J].

CHEN, CT ;

WANG, YB ;

WU, BC ;

WU, KC ;

ZENG, WL ;

YU, LH .

NATURE, 1995, 373 (6512) :322-324

[3] Ba2NaCIP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure [J].

Chen, Jie ;

Xiong, Lin ;

Chen, Ling ;

Wu, Li-Ming .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (43) :14082-14086

[4] CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)-type Structure [J].

Dong, Xuehua ;

Huang, Ling ;

Hu, Cuifang ;

Zeng, Hongmei ;

Lin, Zhien ;

Wang, Xin ;

Ok, Kang Min ;

Zou, Guohong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (20) :6528-6534

[5] Perfect balance harmony in Ba2NO3(OH)3: a beryllium-free nitrate as a UV nonlinear optical material [J].

Dong, Xuehua ;

Huang, Ling ;

Liu, Qingyu ;

Zeng, Hongmei ;

Lin, Zhien ;

Xu, Dingguo ;

Zou, Guohong .

CHEMICAL COMMUNICATIONS, 2018, 54 (45) :5792-5795

[6]

Durif A., 1995, CRYSTAL CHEM CONDENS, P187, DOI [10.1007/978-1-4757-9894-4_4, DOI 10.1007/978-1-4757-9894-4_4]

[7] A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels [J].

Feng, Yuquan ;

Li, Min ;

Fan, Huitao ;

Huang, Qunzeng ;

Qiu, Dongfang ;

Shi, Hengzhen .

DALTON TRANSACTIONS, 2015, 44 (03) :894-897

[8] BaBe2BO3F3: A KBBF-Type Deep-Ultraviolet Nonlinear Optical Material with Reinforced [Be2BO3F2]∞ Layers and Short Phase-Matching Wavelength [J].

Guo, Shu ;

Jiang, Xingxing ;

Liu, Lijuan ;

Xia, Mingjun ;

Fang, Zhi ;

Wang, Xiaoyang ;

Lin, Zheshuai ;

Chen, Chuangtian .

CHEMISTRY OF MATERIALS, 2016, 28 (24) :8871-8875

[9] LiRb2PO4: a new deep-ultraviolet nonlinear optical phosphate with a large SHG response [J].

Li, Lin ;

Wang, Ying ;

Lei, Bing-Hua ;

Han, Shujuan ;

Yang, Zhihua ;

Li, Hongyi ;

Pan, Shilie .

JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (02) :269-274

[10] A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response [J].

Li, Lin ;

Wang, Ying ;

Lei, Bing-Hua ;

Han, Shujuan ;

Yang, Zhihua ;

Poeppelmeier, Kenneth R. ;

Pan, Shilie .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (29) :9101-9104

← 1 2 3 4 5 →