Controlling hydrogen evolution reaction activity on Ni core-Pt island nanoparticles by tuning the size of the Pt islands

被引:10
作者
Alinezhad, Ali [1 ]
Benedetti, Tania M. [1 ]
Lian, Jiaxin [1 ]
Goncales, Vinicius R. [1 ]
Gooding, J. Justin [1 ,2 ,3 ]
Tilley, Richard D. [1 ,3 ,4 ]
机构
[1] Univ New South Wales, Sch Chem, Sydney, NSW 2052, Australia
[2] Univ New South Wales, Australian Ctr Nanomed, Sydney, NSW 2052, Australia
[3] Univ New South Wales, ARC Ctr Excellence Convergent Bionano Sci & Techn, Sydney, NSW 2052, Australia
[4] Univ New South Wales, Mark Wainwright Analyt Ctr, Electron Microscope Unit, Sydney, NSW 2052, Australia
基金
澳大利亚研究理事会;
关键词
D O I
10.1039/d0cc07769k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pt islands with different sizes were grown on amorphous Ni nanoparticles, allowing the tuning of the Pt-Ni interface without changing the hydrogen binding energy of the Pt sites. As a result, the HER activity of the electrocatalysts increases by decreasing the size of the Pt islands due to the greater surface area of the Pt-Ni interfaces.
引用
收藏
页码:2788 / 2791
页数:4
相关论文
共 32 条
[1]   Controlling Pt Crystal Defects on the Surface of Ni-Pt Core-Shell Nanoparticles for Active and Stable Electrocatalysts for Oxygen Reduction [J].
Alinezhad, Ali ;
Benedetti, Tania M. ;
Gloag, Lucy ;
Cheong, Soshan ;
Watt, John ;
Chen, Hsiang-Sheng ;
Gooding, J. Justin ;
Tilley, Richard D. .
ACS APPLIED NANO MATERIALS, 2020, 3 (06) :5995-6000
[2]   Direct Growth of Highly Strained Pt Islands on Branched Ni Nanoparticles for Improved Hydrogen Evolution Reaction Activity [J].
Alinezhad, Ali ;
Gloag, Lucy ;
Benedetti, Tania M. ;
Cheong, Soshan ;
Webster, Richard F. ;
Roelsgaard, Martin ;
Iversen, Bo B. ;
Schuhmann, Wolfgang ;
Gooding, J. Justin ;
Tilley, Richard D. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (41) :16202-16207
[3]   Platinum-nickel alloy excavated nano-multipods with hexagonal close-packed structure and superior activity towards hydrogen evolution reaction [J].
Cao, Zhenming ;
Chen, Qiaoli ;
Zhang, Jiawei ;
Li, Huiqi ;
Jiang, Yaqi ;
Shen, Shouyu ;
Fu, Gang ;
Lu, Bang-an ;
Xie, Zhaoxiong ;
Zheng, Lansun .
NATURE COMMUNICATIONS, 2017, 8 :15131
[4]   Controlled Design of Size-Tunable Monodisperse Nickel Nanoparticles [J].
Carenco, Sophie ;
Boissiere, Cedric ;
Nicole, Lionel ;
Sanchez, Clement ;
Le Floch, Pascal ;
Mezailles, Nicolas .
CHEMISTRY OF MATERIALS, 2010, 22 (04) :1340-1349
[5]   Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces [J].
Chen, Chen ;
Kang, Yijin ;
Huo, Ziyang ;
Zhu, Zhongwei ;
Huang, Wenyu ;
Xin, Huolin L. ;
Snyder, Joshua D. ;
Li, Dongguo ;
Herron, Jeffrey A. ;
Mavrikakis, Manos ;
Chi, Miaofang ;
More, Karren L. ;
Li, Yadong ;
Markovic, Nenad M. ;
Somorjai, Gabor A. ;
Yang, Peidong ;
Stamenkovic, Vojislav R. .
SCIENCE, 2014, 343 (6177) :1339-1343
[6]   Highly Dispersed Platinum on Honeycomb-like NiO@Ni Film as a Synergistic Electrocatalyst for the Hydrogen Evolution Reaction [J].
Chen, Zheng-Jun ;
Cao, Guo-Xuan ;
Gan, Li-Yong ;
Dai, Hao ;
Xu, Ning ;
Zang, Ming-Jie ;
Dai, Hong-Bin ;
Wu, Hui ;
Wang, Ping .
ACS CATALYSIS, 2018, 8 (09) :8866-8872
[7]   DETERMINATION OF ADSORPTION OF OPD H SPECIES IN THE CATHODIC HYDROGEN EVOLUTION REACTION AT PT IN RELATION TO ELECTROCATALYSIS [J].
CONWAY, BE ;
BAI, L .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 198 (01) :149-175
[8]   Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH)2/Metal Catalysts [J].
Danilovic, N. ;
Subbaraman, Ram ;
Strmcnik, D. ;
Chang, Kee-Chul ;
Paulikas, A. P. ;
Stamenkovic, V. R. ;
Markovic, Nenad M. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (50) :12495-12498
[9]   Platinum nanofilm formation by EC-ALE via redox replacement of UPD copper: Studies using in-situ scanning tunneling microscopy [J].
Kim, Youn-Geun ;
Kim, Jay Y. ;
Vairavapandian, Deepa ;
Stickney, John L. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (36) :17998-18006
[10]   Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media [J].
Li, Jingkun ;
Ghoshal, Shraboni ;
Bates, Michael K. ;
Miller, Todd E. ;
Davies, Veronica ;
Stavitski, Eli ;
Attenkofer, Klaus ;
Mukerjee, Sanjeev ;
Ma, Zi-Feng ;
Jia, Qingying .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (49) :15594-15598