Preparation of Fe3O4-C18 nano-magnetic composite materials and their cleanup properties for organophosphorous pesticides

被引：97

作者：

Shen, Hao-Yu

Zhu, Yong

Wen, Xia-Er

Zhuang, Yu-Miao

机构：

[1] Zhejiang Univ, Ningbo Inst Technol, Anal & Testing Ctr, Ningbo 315100, Zhejiang, Peoples R China

[2] Minist Agr, Ningbo Agr Prod Qual Inspect & Testing Ctr, Ningbo 315040, Zhejiang, Peoples R China

来源：

ANALYTICAL AND BIOANALYTICAL CHEMISTRY | 2007年 / 387卷 / 06期

关键词：

magnetic Fe3O4-C18 composite nanoparticles; organophosphorous pesticides; cleanup and enrichment; gas chromatography in combination with a nitrogen/phosphorus detector;

D O I：

10.1007/s00216-006-1082-1

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Magnetic Fe3O4-C18 composite nanoparticles of approximately 5-10 nm in size were synthesized and characterized by IR spectroscopy, atomic absorption spectroscopy, X-ray diffraction, and transmission electron microscopy. The magnetic Fe3O4-C18 composite nanoparticles were applied for cleanup and enrichment of organophosphorous pesticides. Comparative studies were carried out between magnetic Fe3O4-C18 composite nanoparticles and common C18 materials. Residues of organophosphorous pesticides were determined by gas chromatography in combination with a nitrogen/phosphorus detector. The cleanup and enrichment properties of magnetic Fe3O4-C18 composite nanoparticles are comparable with those of common C18 materials for enrichment of organophosphorous pesticides, but the cleanup and enrichment are faster and easier to perform.

引用

页码：2227 / 2237

页数：11

共 35 条

[31] Determination of the limits of identification and quantitation of selected organochlorine and organophosphorous pesticide residues in surface water by full-scan gas chromatography/mass spectrometry [J].