Photophysical properties and photoinduced electron transfer between [60]fullerene-containing cyclic sulphoxide C60-C6H8SO] and tetrathiafulvalene TTF by laser flash photolysis

被引:0
|
作者
Zeng, HP [1 ]
机构
[1] S China Normal Univ, Dept Chem, Guangzhou 510631, Guangdong, Peoples R China
关键词
laser flash photolysis; 60]fullerene-containing cyclic sulphodde; tetrathiafulvalene;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photoinduced electron transfer (PEr) Processes between C-60-C6H8SO and Tetrathiafuvalene (TIF) have been studied by nanosecond laser photolysis. Quantani yields (Phi(et)) and rate constants of electron transfer (k(et)) from TIF to excited triplet state of [60] fallerene-containing cyclic sulphoxide in benzonitrile (BN) have been evaluated by observing the transient absorption bands in the NIR region. With the decay of excited triplet state of [60]fullerene-containing cyclic sulphoxide, the rise of radical anion of [60]fullerene-containing cyclic sulphoxide is observed.
引用
收藏
页码:1007 / 1011
页数:5
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