Aerobic oxidative carboxylation of olefins with metalloporphyrin catalysts

被引:60
作者
Bai, Dongsheng [1 ]
Jing, Huanwang [1 ]
机构
[1] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON-DIOXIDE; CYCLIC CARBONATES; STYRENE CARBONATE; IONIC LIQUIDS; ORGANIC CARBONATES; CHEMICAL FIXATION; COUPLING REACTIONS; SALEN COMPLEXES; CO2; FIXATION; EPOXIDES;
D O I
10.1039/b916042f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dioxo( tetraphenylporphyrinato) ruthenium(VI) and quaternary onium salt were successfully developed as catalysts to initiate a three component reaction of olefin, O-2, and CO2 at ambient temperature under low pressure. The reaction can be carried out under solvent-free or solvent conditions. Styrene carbonate was obtained in 76% yield with 100% selectivity using 4 mol% of catalyst under optimized conditions.
引用
收藏
页码:39 / 41
页数:3
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