Aerobic oxidative carboxylation of olefins with metalloporphyrin catalysts

被引：60

作者：

Bai, Dongsheng ^{[1
]}

Jing, Huanwang ^{[1
]}

机构：

[1] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 01期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; CYCLIC CARBONATES; STYRENE CARBONATE; IONIC LIQUIDS; ORGANIC CARBONATES; CHEMICAL FIXATION; COUPLING REACTIONS; SALEN COMPLEXES; CO2; FIXATION; EPOXIDES;

D O I：

10.1039/b916042f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dioxo( tetraphenylporphyrinato) ruthenium(VI) and quaternary onium salt were successfully developed as catalysts to initiate a three component reaction of olefin, O-2, and CO2 at ambient temperature under low pressure. The reaction can be carried out under solvent-free or solvent conditions. Styrene carbonate was obtained in 76% yield with 100% selectivity using 4 mol% of catalyst under optimized conditions.

引用

收藏

页码：39 / 41

页数：3

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