Aerobic oxidative carboxylation of olefins with metalloporphyrin catalysts

被引：62

作者：

Bai, Dongsheng ^{[1
]}

Jing, Huanwang ^{[1
]}

机构：

[1] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 01期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; CYCLIC CARBONATES; STYRENE CARBONATE; IONIC LIQUIDS; ORGANIC CARBONATES; CHEMICAL FIXATION; COUPLING REACTIONS; SALEN COMPLEXES; CO2; FIXATION; EPOXIDES;

D O I：

10.1039/b916042f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dioxo( tetraphenylporphyrinato) ruthenium(VI) and quaternary onium salt were successfully developed as catalysts to initiate a three component reaction of olefin, O-2, and CO2 at ambient temperature under low pressure. The reaction can be carried out under solvent-free or solvent conditions. Styrene carbonate was obtained in 76% yield with 100% selectivity using 4 mol% of catalyst under optimized conditions.

引用

收藏

页码：39 / 41

页数：3

相关论文

共 34 条

[1] CO2 fixation using recoverable chromium salen catalysts:: use of ionic liquids as cosolvent or high-surface-area silicates as supports [J].

Alvaro, M ;

Baleizao, C ;

Das, D ;

Carbonell, E ;

García, H .

JOURNAL OF CATALYSIS, 2004, 228 (01) :254-258

[2] Carbon dioxide as building block for the synthesis of organic carbonates - Behavior of homogeneous and heterogeneous catalysts in the oxidative carboxylation of olefins [J].

Aresta, M ;

Dibenedetto, A .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) :399-409

[3] DIRECT SYNTHESIS OF 1,3-BENZODIOXOL-2-ONE FROM STYRENE, DIOXYGEN AND CARBON-DIOXIDE PROMOTED BY RH(I) [J].

ARESTA, M ;

QUARANTA, E ;

CICCARESE, A .

JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (03) :355-359

[4]

Aresta M, 2000, APPL ORGANOMET CHEM, V14, P799, DOI 10.1002/1099-0739(200012)14:12<799::AID-AOC82>3.0.CO

[5]

2-8

[6] Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts [J].

Caló, V ;

Nacci, A ;

Monopoli, A ;

Fanizzi, A .

ORGANIC LETTERS, 2002, 4 (15) :2561-2563

[7] Copolymerization of CO2 and epoxides catalyzed by metal salen complexes [J].

Darensbourg, DJ ;

Mackiewicz, RM ;

Phelps, AL ;

Billodeaux, DR .

ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (11) :836-844

[8] Catalysts for the reactions of epoxides and carbon dioxide [J].

Darensbourg, DJ ;

Holtcamp, MW .

COORDINATION CHEMISTRY REVIEWS, 1996, 153 :155-174

[9] Conversion of carbon dioxide and olefins into cyclic carbonates in water [J].

Eghbali, Nicolas ;

Li, Chao-Jun .

GREEN CHEMISTRY, 2007, 9 (03) :213-215

[10] AEROBIC EPOXIDATION OF OLEFINS WITH RUTHENIUM PORPHYRIN CATALYSTS [J].

GROVES, JT ;

QUINN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (20) :5790-5792

← 1 2 3 4 →