Chiral self-discrmination in a M3L2 subphthalocyanine cage

被引：155

作者：

Claessens, CG ^{[1
]}

Torres, T ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 49期

关键词：

D O I：

10.1021/ja028705j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tris(3-pyridyl)-substituted C3 symmetric subphthalocyanine (SubPc) was dimerized into a M3L2 cage in the presence of a stoichiometric amount of (en)Pd(NO3)2. NMR studies demonstrated the recognition event to be accompanied by chiral self-discrimination between the two enantiomers of the SubPc. Moreover, the specificity is such that only one of four possible isomers was detected in solution. Copyright © 2002 American Chemical Society.

引用

页码：14522 / 14523

页数：2

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