Synthesis, structure, and properties of a new 3D hydrogen-bonded porous coordination polymer

被引：3

作者：

Ji, J. W. ^{[1
]}

Han, Z. B. ^{[1
]}

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 01期

关键词：

METAL-ORGANIC FRAMEWORK; SINGLE-CRYSTAL TRANSFORMATIONS; PERMANENT POROSITY; NETWORK; CHEMISTRY; EXCHANGE; SOLIDS; ZN(II); LIGAND; CHAINS;

D O I：

10.1134/S1070328410010069

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new coordination polymer, [Cd(HMal)(Bipy)(H2O) center dot 2H(2)O (I) (H(3)Mal is malic acid, Bipy is 4,4'-bipyridine), has been synthesized from H(3)Mal and Bipy under hydrothermal conditions and characterized by elemental analysis, IR, TG, and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that I (C14H16N2O7Cd) crystallizes in the orthorhombic system, space group Ibam. The adjacent cadmium(II) atoms were first interconnected by the HMal ligands via carboxylate oxygen atoms and its adjacent hydroxyl group to generate an infinite zigzag [Cd(HMal)] (n) chain, which are further linked by Bipy ligands to form a 2D wavelike layer. Interestingly, the adjacent layers are further connected via hydrogen bonds, giving rise to a 3D porous framework with a cross-sectional area of 11.690 x 9.326 (2). The unit cell parameters for I: a = 8,457(1), b = 22.030(7), c = 23.066(7) V = 4297(2) (3), Z = 4.

引用

页码：37 / 42

页数：6

共 40 条

[1]

Abrahams BF, 1998, ANGEW CHEM INT EDIT, V37, P2656, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2656::AID-ANIE2656>3.0.CO

[2]

2-M

[3]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[4]

2-Z

[5] Expanded Prussian blue analogues incorporating [Re6Se8(CN)6]3-/4- clusters:: Adjusting porosity via charge balance [J].

Bennett, MV ;

Beauvais, LG ;

Shores, MP ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8022-8032

[6] Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co5(bpe)9(H2O)8(SO4)4](SO4)•14H2O [bpe=1,2-bis(4-pyridyl)ethane] [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM ;

Rizzato, S .

CHEMICAL COMMUNICATIONS, 2000, (14) :1319-1320

[7] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

[8] Dynamic and redox active pillared bilayer open framework: Single-crystal-to-single-crystal transformations upon guest removal, guest exchange, and framework oxidation [J].

Choi, HJ ;

Suh, MP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (48) :15844-15851

[9] A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity [J].

Dybtsev, DN ;

Nuzhdin, AL ;

Chun, H ;

Bryliakov, KP ;

Talsi, EP ;

Fedin, VP ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :916-920

[10] Crystal engineering of nonlinear optical materials based on interpenetrated diamondoid coordination networks [J].

Evans, OR ;

Lin, WB .

CHEMISTRY OF MATERIALS, 2001, 13 (08) :2705-2712

← 1 2 3 4 →