The Mechanical/Thermal Properties of Microcellular Injection-Molded Poly-Lactic-Acid Nanocomposites

被引:32
作者
Hwang, Shyh-Shin [1 ]
Hsu, Peming P. [2 ]
Yeh, Jui-Ming [3 ,4 ]
Chang, Kung-Chin [3 ,4 ]
Lai, Ying-Zhong [1 ]
机构
[1] Ching Yun Univ, Dept Mech Engn, Chungli 32023, Taiwan
[2] Far E Univ, Dept Mech Engn, Tainan 74420, Taiwan
[3] Chung Yuan Christian Univ, Dept Chem, Chungli 32023, Taiwan
[4] Chung Yuan Christian Univ, Ctr Nanotechnol, Chungli 32023, Taiwan
关键词
SILICATE NANOCOMPOSITES;
D O I
10.1002/pc.20736
中图分类号
TB33 [复合材料];
学科分类号
摘要
This study investigated the influence of montmorillonite (MMT) content on the mechanical/thermal properties of microcellular injection-molded polylactide (PLA)/clay nanocomposites. Carbon dioxide was the blowing agent. The PLA/MMT nanocomposites were prepared by twin screw extrusion. The results showed that as MMT content is increased, tensile strength, impact strength, and cell density decrease. This is caused by the speed degradation of PLA due to the addition of MMT. MMT decreases the crystallization temperature but increases the decomposition temperature of the nanocomposites. The XRD results showed that the layer spacing of the clay increases as MMT content increases. TEM pictures showed that the MMT is well dispersed within the PLA matrix. POLYM. COMPOS., 30:1625-1630, 2009. (c) 2008 Society of Plastics Engineers
引用
收藏
页码:1625 / 1630
页数:6
相关论文
共 17 条
[1]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[2]   Microstructure and crystallography in microcellular injection-molded polyamide-6 nanocomposite and neat resin [J].
Chandra, A ;
Gong, SQ ;
Yuan, MJ ;
Turng, LS ;
Gramann, P ;
Cordes, H .
POLYMER ENGINEERING AND SCIENCE, 2005, 45 (01) :52-61
[3]   Poly(lactic acid)/organoclay nanocomposites: Thermal, rheological properties and foam processing [J].
Di, YW ;
Iannace, S ;
Di Maio, E ;
Nicolais, L .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2005, 43 (06) :689-698
[4]   Well-controlled biodegradable nanocomposite foams: From microcellular to nanocellular [J].
Fujimoto, Y ;
Ray, SS ;
Okamoto, M ;
Ogami, A ;
Yamada, K ;
Ueda, K .
MACROMOLECULAR RAPID COMMUNICATIONS, 2003, 24 (07) :457-461
[5]   Flammability properties of polymer - Layered-silicate nanocomposites. Polypropylene and polystyrene nanocomposites [J].
Gilman, JW ;
Jackson, CL ;
Morgan, AB ;
Harris, R ;
Manias, E ;
Giannelis, EP ;
Wuthenow, M ;
Hilton, D ;
Phillips, SH .
CHEMISTRY OF MATERIALS, 2000, 12 (07) :1866-1873
[6]   Continuous microcellular polystyrene foam extrusion with supercritical CO2 [J].
Han, XM ;
Koelling, KW ;
Tomasko, DL ;
Lee, LJ .
POLYMER ENGINEERING AND SCIENCE, 2002, 42 (11) :2094-2106
[7]   Polymer nanocomposite foams [J].
Lee, LJ ;
Zeng, CC ;
Cao, X ;
Han, XM ;
Shen, J ;
Xu, GJ .
COMPOSITES SCIENCE AND TECHNOLOGY, 2005, 65 (15-16) :2344-2363
[8]  
Lee S.T., 2000, FOAM EXTRUSION PRINC
[9]  
LI T, 2005, SPE ANTEC, P759
[10]   Poly(lactic acid):: plasticization and properties of biodegradable multiphase systems [J].
Martin, O ;
Avérous, L .
POLYMER, 2001, 42 (14) :6209-6219