Non-linear relaxation of the photo-induced high spin state in spin-crossover solids: Effect of correlations

被引:13
作者
Boukheddaden, K [1 ]
Varret, F [1 ]
Salunke, S [1 ]
Linares, J [1 ]
Codjovi, E [1 ]
机构
[1] Univ Versailles, CNRS, Lab Magnetisme & Opt, F-78035 Versailles, France
关键词
spin-crossover; high-spin; low-spin; mean-field;
D O I
10.1080/01411590290033840
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We investigate a microscopic model based on the pair approximation, for the dynamical properties of the photo-induced high-spin state in spin-crossover solids at low temperature. The model uses the Ising-like hamiltonian and combines long- and short-range interactions. The stochastic treatment of the latter provides a set of two coupled differential equations for the macroscopic short- and long-range order parameters, which reproduce successfully the main features of the experimental relaxation curves.
引用
收藏
页码:733 / 741
页数:9
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