Photocontrolled nucleobase binding to an organometallic RuII arene complex

被引：93

作者：

Betanzos-Lara, Soledad ^{[1
]}

Salassa, Luca ^{[1
]}

Habtemariam, Abraha ^{[1
]}

Sadler, Peter J. ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 43期

关键词：

ANTICANCER COMPLEXES; MOLECULAR CALCULATIONS; DNA; DENSITY; CANCER; PHOTOCHEMISTRY; CHEMISTRY; ADDUCTS; GUANINE; AGENTS;

D O I：

10.1039/b914153g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [(p-cym)Ru(bpm)(py)][PF6](2) (where p-cym = para-cymene, bpm = 2,2'-bipyrimidine and py = pyridine) is the first ruthenium(II) arene complex that can selectively photodissociate a monodentate ligand (py) when excited with visible light and form a reactive aqua derivative able to bind to a DNA base.

引用

页码：6622 / 6624

页数：3

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