Radiolytic reduction of Fe(II) in 2-propanol

被引：13
作者：
Dey, G. R. [1 ]
Remita, H. [1 ]
Mostafavi, M. [1 ]
机构：
[1] Univ Paris 11, CNRS, UMR 8000, Chim Phys Lab,Ctr Orsay, F-91405 Orsay, France
来源：
CHEMICAL PHYSICS LETTERS | 2006年 / 431卷 / 1-3期
关键词：
D O I：
10.1016/j.cplett.2006.09.055
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The first reduction steps of iron (11) in 2-propanol have been studied by pulse radiolysis technique. The rate constant value of the reaction of solvated electron with iron (II) was found to be 4.8x10(9) dm(3) mol(-1) s(-1). The absorption spectrum of Fe(I) with a maximum at 350 nm was determined. The radiolytic reduction of Fe-11 in 2-propanol under an inert atmosphere leads to the formation of very small iron nanoparticles whereas under a CO atmosphere, the stable Fe(CO)5 complex is formed. (c) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：83 / 87
页数：5
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