Carbon nanotubes-CuO/SnO2 based gas sensor for detecting H2S in low concentration

被引:29
作者
Fan, Jun [1 ]
Liu, Ping [1 ]
Chen, Xiaohong [1 ]
Zhou, Honglei [1 ]
Fu, Shaoli [1 ]
Wu, Wanwan [1 ]
机构
[1] Univ Shanghai Sci & Technol, Sch Mat Sci & Engn, Shanghai 200093, Peoples R China
基金
美国国家科学基金会;
关键词
CuO/SnO2; semiconductors; carbon nanotubes; H2S; gas sensors; SENSING PERFORMANCE; FABRICATION;
D O I
10.1088/1361-6528/ab3cb3
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Porous CuO/SnO2 nanofibers were prepared by co-dissolution and electrospinning, followed by annealing, and compounded with different amounts of carbon nanotubes (CNTs, 0-5 wt%). The performance of the composite based sensor was tested in different concentrations of H2S range from 0.1 to 0.5 ppm. The results showed that the gas sensor based CuO/SnO2 doped by CNTs (CNTs-CuO/SnO2) has a low optimum operating temperature, 40 degrees C, good behavior in detecting low concentration H2S, short response and recovery time (8.3 and 11.5 s, respectively). And at the same time, compared with other gases, 3 wt% CNTs-CuO/SnO2 composite nanomaterial had excellent selectivity to H2S at low concentrations. The prepared gas sensor had great advantages in detecting low concentration H2S.
引用
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页数:6
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共 22 条
[1]   Aerosol-Assisted CVD-Grown WO3 Nanoneedles Decorated with Copper Oxide Nanoparticles for the Selective and Humidity-Resilient Detection of H2S [J].
Annanouch, Fatima E. ;
Haddi, Zouhair ;
Vallejos, Stella ;
Umek, Polona ;
Guttmann, Peter ;
Bittencourt, Carla ;
Llobet, Eduard .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (12) :6842-6851
[2]   Synthesis of SnO2-CuO heterojunction using electrospinning and application in detecting of CO [J].
Bai, Shouli ;
Guo, Wentao ;
Sun, Jianhua ;
Li, Jiao ;
Tian, Ye ;
Chen, Aifan ;
Luo, Ruixian ;
Li, Dianqing .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 226 :96-103
[3]   Ultraselective and ultrasensitive detection of H2S in highly humid atmosphere using CuO-loaded SnO2 hollow spheres for real-time diagnosis of halitosis [J].
Choi, Kwon-Il ;
Kim, Hyo-Joong ;
Kang, Yun Chan ;
Lee, Jong-Heun .
SENSORS AND ACTUATORS B-CHEMICAL, 2014, 194 :371-376
[4]   Highly sensitive and selective H2S sensor based on porous ZnFe2O4 nanosheets [J].
Gao, Xinming ;
Sun, Yue ;
Zhu, Chunling ;
Li, Chunyan ;
Ouyang, Qiuyun ;
Chen, Yujin .
SENSORS AND ACTUATORS B-CHEMICAL, 2017, 246 :662-672
[5]   Fe2O3 nanomaterials derived from Prussian blue with excellent H2S sensing properties [J].
Guo, Yicheng ;
Tian, Xianqing ;
Wang, Xinfeng ;
Sun, Jie .
SENSORS AND ACTUATORS B-CHEMICAL, 2019, 293 :136-143
[6]   Development of sensors based on CuO-doped SnO2 hollow spheres for ppb level H2S gas sensing [J].
He, Lifang ;
Jia, Yong ;
Meng, Fanli ;
Li, Minqiang ;
Liu, Jinhuai .
JOURNAL OF MATERIALS SCIENCE, 2009, 44 (16) :4326-4333
[7]   Enhancement of H2S sensing performance of p-CuO nanofibers by loading p-reduced graphene oxide nanosheets [J].
Kim, Jae-Hun ;
Mirzaei, Ali ;
Zheng, Yifang ;
Lee, Jae-Hyoung ;
Kim, Jin-Young ;
Kim, Hyoun Woo ;
Kim, Sang Sub .
SENSORS AND ACTUATORS B-CHEMICAL, 2019, 281 :453-461
[8]   Sensors for Breath Testing: From Nanomaterials to Comprehensive Disease Detection [J].
Konvalina, Gady ;
Haick, Hossam .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (01) :66-76
[9]   Effect of single wall carbon nanotube networks on gas sensor response and detection limit [J].
Kumar, Deepak ;
Chaturvedi, Poornendu ;
Saho, Praveen ;
Jha, Pika ;
Chouksey, Abhilasha ;
Lal, Mohan ;
Rawat, J. S. B. S. ;
Tandon, R. P. ;
Chaudhury, P. K. .
SENSORS AND ACTUATORS B-CHEMICAL, 2017, 240 :1134-1140
[10]   Synthesis and improved ethanol sensing performance of CuO/SnO2 based hollow microspheres [J].
Li, Meihua ;
Zhu, Huichao ;
Cheng, Jing ;
Zhao, Mingming ;
Yan, Weiping .
JOURNAL OF POROUS MATERIALS, 2017, 24 (02) :507-518