Capillary zone electrophoresis of iridium(III) and ruthenium(II) polypyridyl complexes in non-aqueous solvents

被引：3
作者：
Pauw, Brian R.
Holder, Elisabeth
Marin, Veronica
Lohmeijer, Bas G. G.
Schubert, Ulrich S. [1 ]
机构：
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, Eindhoven, Netherlands
[2] Dutch Polymer Inst, Eindhoven, Netherlands
来源：
ANALYTICAL LETTERS | 2007年 / 40卷 / 01期
关键词：
capillary zone electrophoresis; separation; mobility; polypyridyl complexes; metal-containing polymers;
D O I：
10.1080/00032710600952614
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A method of non-aqueous capillary zone electrophoresis has been optimized for the characterization of five functionalized mixed-ligand iridium(III) polypyridyl complexes and four functionalized ruthenium(II) bis-terpyridine complexes. Their mobilities, the relation to their molar mass, and the capillary lifetime (measured in number of injections) have been determined.
引用
收藏
页码：163 / 171
页数：9
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