Solid-liquid equilibria of the ternary system m-nitrobenzoic acid plus p-nitrobenzoic acid plus acetone

被引:1
作者
Zhao Hongkun [1 ]
Meng Xianchao [1 ]
Jian Panming [1 ]
机构
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
关键词
Nitrobenzoic acid; Acetone; Solid-liquid equilibria; PHASE-DIAGRAM; 283.15; K;
D O I
10.1016/j.fluid.2009.07.011
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubility data and the density of equilibrium liquid phase for the ternary system m-nitrobenzoic acid + p-nitrobenzoic acid + acetone were determined at 283.1 K and 313.1 K, and the phase diagrams of the system were constructed. Two solid phases, pure solid m-nitrobenzoic acid and p-nitrobenzoic acid are confirmed by the Schreinemaker's wet residue method. The crystallization regions of m-nitrobenzoic acid and p-nitrobenzoic acid increase as the temperature decreases. At the same temperature, the crystallization region of p-nitrobenzoic acid is larger than that of m-nitrobenzoic acid. (C) 2009 Elsevier B.V. All rights reserved.
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页码:97 / 100
页数:4
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