Thermodynamics of solvation of proton and chloride ion in alcohols

被引：0

作者：

Bulavin, VI ^{[1
]}

机构：

[1] Kharkov State Polytech Univ, Kharkov, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 1999年 / 69卷 / 12期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method is proposed for estimating the solvation entropy, enthalpy, and Gibbs free energy of individual H+ and Cl- ions in a series of alcohols, based on the previously derived correlation equations. Proton and chloride ion solvation in a series of alcohols from methanol to nonanol at 278.15-328.15 K (at a 10 K step) is thermodynamically analyzed. It is shown that the solvation of hydrogen chloride is essentially determined by proton solvation.

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页码：1875 / 1878

页数：4

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