Density, Speed of Sound, and Refractive Index of the Binary Systems Cyclohexane (1) or Methylcyclohexane (1) or Cyclo-octane (1) with Benzene (2), Toluene (2), and Ethylbenzene (2) at Two Temperatures

被引:69
作者
Gonzalez, Begona [1 ]
Dominguez, Irene [1 ]
Gonzalez, Emilio J. [1 ]
Dominguez, Angeles [1 ]
机构
[1] Univ Vigo, Dept Ingn Quim, Vigo 36310, Spain
关键词
EXCESS MOLAR VOLUMES; PLUS CYCLOHEXANE; ISENTROPIC COMPRESSIBILITIES; LIQUID-EQUILIBRIA; MIXTURES; CYCLOALKANES; 298.15-K; HYDROCARBONS;
D O I
10.1021/je900468u
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities, speeds of sound, and refractive indices of binary systems containing cycloalkanes (cyclohexane and methylcyclohexane) with aromatic compounds (benzene, toluene, and ethylbenzene) at T = (283.15 and 298.15) K and cyclo-octane with aromatic compounds at T = 298.15 K under atmospheric pressure were determined over the whole composition range. From the experimental results, the derived and excess properties (excess molar volumes, isentropic compression, excess molar isentropic compressibility, and refractive index deviations) at T = (283.15 and 298.15) K were calculated and satisfactorily fitted to the Redlich-Kister equation.
引用
收藏
页码:1003 / 1011
页数:9
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