The first example of a cis-platinum analogue with two directly bridged imidazoles: [Pt(mimim)Cl-2]center dot Et(4)NCl

被引：12

作者：

Karentzopoulos, S

Engelking, H

Bremer, B

Paschke, N

Krebs, B

机构：

[1] Anorganisch-Chemisches Institut, Westfälische Wilhelms-Univ., D-48149 Münster

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270196011948

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the title compound, tetraethylammonium dichloro(1-methyl-2,2'-biimidazole-N-3,N-3')-platinum(II) chloride, (C8H20N)[PtCl2(C7H8N4)]Cl, has been determined from single-crystal X-ray diffraction data. The square-planar coordination sphere of the platinum consists of two N atoms of the biimidazole ligand and two Cl atoms in a cis arrangement. The average Pt-N and Pt-Cl distances are 2.017 and 2.309 Angstrom, respectively. One Et(4)NCl molecule co-crystallizes in the asymmetric unit.

引用

页码：172 / 174

页数：3

共 21 条

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