A simplified green chemistry approaches to organic synthesis in solid media. Activated fly ash, an industrial waste (pollutant) as an efficient and novel catalyst for some selected organic reactions in solvent-free conditions under microwave irradiation

被引：53

作者：

Gopalakrishnan, M. ^{[1
]}

Sureshkumar, P. ^{[1
]}

Kanagarajan, V. ^{[1
]}

Thanusu, J. ^{[1
]}

Govindaraju, R. ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, India

来源：

ARKIVOC | 2006年

关键词：

activated fly ash; Knoevenagel condensation; Beckmann rearrangement; Schiff bases formation; Biginelli and Hantzsch reactions;

D O I：

10.3998/ark.5550190.0007.d13

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Activated Fly ash, an industrial waste (pollutant) is found to be well suited for catalyzing reactions which are having industrial, pharmacological and therapeutic importance, e. g. Knoevenagel condensation, 'One-Pot' conversions of ketones to amides, via, Beckmann rearrangement, Schiff Bases formation, Biginelli and Hantzsch reactions under microwave irradiation in solvent-free conditions. Moreover, this catalyst shows a promising future in that it can provide environmentally clean processes for the chemical industry.

引用

页码：131 / 141

页数：11

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