Mechanical Properties and Creep Behavior of Rotationally Moldable Linear Low-Density Polyethylene-Fumed Silica Nanocomposites

被引:17
作者
Chandran, V. Girish [1 ]
Waigaonkar, Sachin D. [1 ]
机构
[1] Bits Pilani KK Birla Goa Campus, Dept Mech Engn, Zuarinagar 403726, Goa, India
关键词
RECOVERY BEHAVIOR; NONLINEAR CREEP; COMPOSITES; POLYMERIZATION; POLYCARBONATE; RELAXATION; MORPHOLOGY; POLYMERS; FIBERS; MODELS;
D O I
10.1002/pc.23600
中图分类号
TB33 [复合材料];
学科分类号
摘要
Rotationally moldable linear low density polyethylene (LLDPE) is one of the most popular materials used for rotational molding. Yet, incorporation of additives is necessary to improve the mechanical, visco-elastic, thermal as well as melt flow properties of LLDPE. In this article, the influence of fumed silica (FS) nanoparticles on the mechanical properties viz. tensile, flexural, and impact strengths of rotationally moldable LLDPE is investigated. The microstructural studies using SEM were conducted to study the dispersion of FS in LLDPE and correlated with the mechanical properties of the nanocomposites. Dynamic mechanical analysis (DMA) were also carried out to find the time-temperature dependent mechanical properties viz. storage modulus (E'), loss modulus (E ''), and tan delta between 1 and 8 wt% of FS. DMA studies were extended to perform accelerated stepped isothermal creep studies to find out the influence of FS in creep strains. POLYM. COMPOS., 38:421-430, 2017. (C) 2015 Society of Plastics Engineers
引用
收藏
页码:421 / 430
页数:10
相关论文
共 47 条
[1]   The unusual effect of temperature on stress relaxation and mechanical creep of polycarbonate at low strain and stress levels [J].
Abu-Abdeen, M. .
MATERIALS & DESIGN, 2012, 34 :469-473
[2]  
Acha B.A., 2007, COMPOS A, V38
[3]   Accelerated creep testing of polymers using the stepped isothermal method [J].
Achereiner, Frederic ;
Engelsing, Kurt ;
Bastian, Martin ;
Heidemeyer, Peter .
POLYMER TESTING, 2013, 32 (03) :447-454
[4]  
Alwis K.G.N.C., 2008, J MAT SCI, V43
[5]   Effect of polymer/filler interactions on the structure and rheological properties of ethylene-octene copolymer/nanosilica composites [J].
Bailly, Mathieu ;
Kontopoulou, Marianna ;
El Mabrouk, Khalil .
POLYMER, 2010, 51 (23) :5506-5515
[6]  
Barthel H, 1999, PART PART SYST CHAR, V16, P169, DOI 10.1002/(SICI)1521-4117(199908)16:4<169::AID-PPSC169>3.0.CO
[7]  
2-H
[8]   Viscoelastic properties and morphological characterization of silica/polystyrene nanocomposites synthesized by nitroxide-mediated polymerization [J].
Bartholome, C ;
Beyou, E ;
Bourgeat-Lami, E ;
Cassagnau, P ;
Chaumont, P ;
David, L ;
Zydowicz, N .
POLYMER, 2005, 46 (23) :9965-9973
[9]   Simulation of non-isothermal melt densification of polyethylene in rotational molding [J].
Bellehumeur, CT ;
Tiang, JS .
POLYMER ENGINEERING AND SCIENCE, 2002, 42 (01) :215-229
[10]   Predicting Compressive Creep Behavior of Virgin HDPE Using Thermal Acceleration [J].
Bozorg-Haddad, Amir ;
Iskander, Magued .
JOURNAL OF MATERIALS IN CIVIL ENGINEERING, 2011, 23 (08) :1154-1162