[Re(CO)3(5-PAN)Cl], a rhenium(i) naphthalimide complex for the visible light photocatalytic reduction of CO2

被引：12

作者：

Case, Derek R. ^{[1
]}

Spear, Alyssa ^{[1
]}

Henwood, Adam F. ^{[3
,4
]}

Nanao, Max ^{[2
]}

Dampf, Sara ^{[1
]}

Korter, Timothy M. ^{[1
]}

Gunnlaugsson, Thorfinnur ^{[3
,4
]}

Zubieta, Jon ^{[1
]}

Doyle, Robert P. ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, 111 Coll Pl, Syracuse, NY 13244 USA

[2] European Synchrotron Radiat Facil, Struct Biol Grp, 71 Ave Martyrs, F-38000 Grenoble, France

[3] Univ Dublin, Sch Chem, Trinity Coll Dublin, Dublin 2, Ireland

[4] Univ Dublin, Trinity Biomed Sci Inst, Trinity Coll Dublin, Dublin 2, Ireland

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 10期

基金：

爱尔兰科学基金会;

关键词：

Carbon dioxide;

D O I：

10.1039/d0dt04116e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rhenium(i) naphthalimide complex [Re(CO)(3)(5-PAN)Cl] (Re(5-PAN); 5-PAN = 1-(1,10-phenanthroline)-4-nitro-naphthalimide) was synthesized, characterized, and evaluated as a photocatalyst for CO2 reduction. Characterization included use of MALDI-ToF mass spectrometry, FT-IR, RAMAN, H-1 and C-13 NMR, elemental analysis, electronic absorption and emission spectroscopy, single crystal X-ray diffraction, DFT and cyclic voltammetry. Photocatalytic (406 nm) reduction of (CO2)-C-13 to formate ((HCOO)-C-13) in the presence of this catalyst was tracked via(13)C NMR. Results support Re5-PAN (phi = 0.021) functioning as a catalyst for the reduction of CO2 (maximum turn-over 48-50 at 300 equiv. triethylamine as the sacrificial electron donor).

引用

页码：3479 / 3486

页数：8

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