Modification of linear triblock copolymer SBS via olefinic per(poly)fluoroalkylation by per(poly)fluorodiacyl peroxides

被引:6
作者
Zhou, ZB [1 ]
He, HY [1 ]
Weng, ZY [1 ]
Zhao, CX [1 ]
机构
[1] Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
per(poly)fluorodiacyl peroxiaes; fluoroalkylation; SBS; surface modification;
D O I
10.1016/S0022-1139(00)00253-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Facile electron transfer reactions between linear triblock copolymer SBS (polystyrene-polybutadiene-polystyrene) and per(poly)fluorodiacyl peroxides at room temperature (similar to 20 degrees C) in dichloromethane produced high yields of olefmic per(poly)fluoroalkylated SBS with excellent water and oil repellency, chemical resistance and much lowered refractive indices. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:285 / 290
页数:6
相关论文
共 19 条
[1]   POLYMER CHEMISTRY .4. PARTLY FLUORINATED POLYETHERS AS ADDITIVES FOR SURFACE MODIFICATION [J].
BADYAL, JPS ;
CHAMBERS, RD ;
JOEL, AK .
JOURNAL OF FLUORINE CHEMISTRY, 1993, 60 (2-3) :297-300
[2]  
Banks R. E., 1979, ORGANOFLUORINE CHEM
[3]  
BRADY RF, 1990, CHEM BRIT, P427
[4]   PRODUCTION OF PERFLUOROALKYLATED NANOSPHERES FROM BUCKMINSTERFULLERENE [J].
FAGAN, PJ ;
KRUSIC, PJ ;
MCEWEN, CN ;
LAZAR, J ;
PARKER, DH ;
HERRON, N ;
WASSERMAN, E .
SCIENCE, 1993, 262 (5132) :404-407
[5]   REACTIVITY AND REACTION PATTERNS OF ALKYL ALKOXYBENZENE RADICAL CATIONS - MECHANISTIC PATHWAYS OF THE REACTIONS BETWEEN 2,5-DI-TERT-BUTYL-1,4-DIMETHOXYBENZENE AND PERFLUORODIACYL PEROXIDES [J].
JIANG, XK ;
ZHAO, CX ;
GONG, YF .
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1991, 4 (01) :1-6
[6]  
Luo XD, 1999, ACTA POLYM SIN, P623
[7]   PERFLUOROPROPYLATION OF FURANS, THIOPHENES, AND PYRIDINES WITH BIS(HEPTAFLUOROBUTYRYL) PEROXIDE [J].
SAWADA, H ;
YOSHIDA, M ;
HAGII, H ;
AOSHIMA, K ;
KOBAYASHI, M .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (01) :215-219
[8]   SYNTHESIS AND SURFACTANT PROPERTIES OF FLUOROALKYLATED OLIGOMERS CONTAINING CARBOXY GROUPS [J].
SAWADA, H ;
GONG, YF ;
MINOSHIMA, Y ;
MATSUMOTO, T ;
NAKAYAMA, M ;
KOSUGI, M ;
MIGITA, T .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (07) :537-538
[9]   TRIFLUOROMETHYLATION OF AROMATIC-COMPOUNDS WITH BIS(TRIFLUOROACETYL) PEROXIDE [J].
SAWADA, H ;
NAKAYAMA, M ;
YOSHIDA, M ;
YOSHIDA, T ;
KAMIGATA, N .
JOURNAL OF FLUORINE CHEMISTRY, 1990, 46 (03) :423-431
[10]  
SAWADA H, 1990, POLYM COMMUN, V31, P63