Deep eutectic solvents vs ionic liquids: Similarities and differences

被引:385
作者
Plotka-Wasylka, Justyna [1 ]
de la Guardia, Miguel [2 ]
Andruch, Vasil [3 ]
Vilkova, Maria [4 ]
机构
[1] Gdansk Univ Technol, Fac Chem, Dept Analyt Chem, PL-80233 Gdansk, Poland
[2] Univ Valencia, Dept Analyt Chem, Valencia 46100, Spain
[3] Pavol Jozef Safarik Univ Kosice, Fac Sci, Inst Chem, Dept Analyt Chem, SK-04154 Kosice, Slovakia
[4] Pavol Jozef Safarik Univ Kosice, Fac Sci, Inst Chem, Lab NMR, SK-04154 Kosice, Slovakia
关键词
Deep eutectic solvents; Ionic liquids; Analytical chemistry; Solvents; CHOLINE CHLORIDE; PHYSICAL-PROPERTIES; MIXTURES; SALTS; GREEN; ACID;
D O I
10.1016/j.microc.2020.105539
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Deep eutectic solvents (DES) were introduced as an alternative to ionic liquids (IL) to overcome the drawbacks of IL solvents. However, some authors consider them to be a subclass of ILs. In contrast, other authors emphasize that these are by their nature independent, different groups of substances. Thus, the question arises: Which solvent group should DESs belong to? Maybe a new class should be added to the existing ones. The aim of this work is to attract the attention of researchers using DES in their studies to the need for a proper use of terms.
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页数:7
相关论文
共 30 条
[21]  
Ratti R., 2014, ADV CHEM SER, V2014, P1, DOI [DOI 10.1155/2014/729842, 10.1155/2014/729842]
[22]   Menthol-based Eutectic Mixtures: Hydrophobic Low Viscosity Solvents [J].
Ribeiro, Bernardo D. ;
Florindo, Catarina ;
Iff, Lucas C. ;
Coelho, Maria A. Z. ;
Marrucho, Isabel M. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (10) :2469-2477
[23]   Porous Solids Impregnated with Task-Specific Ionic Liquids as Composite Sorbents [J].
Ruckart, K. Neil ;
O'Brien, Richard A. ;
Woodard, Seth M. ;
West, Kevin N. ;
Glover, T. Grant .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (35) :20681-20697
[24]   Application of deep eutectic solvents in analytical chemistry. A review [J].
Shishov, Andrey ;
Bulatov, Andrey ;
Locatelli, Marcello ;
Carradori, Simone ;
Andruch, Vasil .
MICROCHEMICAL JOURNAL, 2017, 135 :33-38
[25]   Ionic liquids synthesis and applications: An overview [J].
Singh, Sandip K. ;
Savoy, Anthony W. .
JOURNAL OF MOLECULAR LIQUIDS, 2020, 297
[26]   Deep Eutectic Solvents (DESs) and Their Applications [J].
Smith, Emma L. ;
Abbott, Andrew P. ;
Ryder, Karl S. .
CHEMICAL REVIEWS, 2014, 114 (21) :11060-11082
[27]   The role of water in deep eutectic solvent-base extraction [J].
Vilkova, Maria ;
Plotka-Wasylka, Justyna ;
Andruch, Vasil .
JOURNAL OF MOLECULAR LIQUIDS, 2020, 304
[28]  
Walden P., 1914, Bull. Acad. Imper. Sci. St. Petersbourg, V8, P405
[29]   Room-temperature ionic liquids. Solvents for synthesis and catalysis [J].
Welton, T .
CHEMICAL REVIEWS, 1999, 99 (08) :2071-2083
[30]   Preparation and determination of phenolic compounds from Pyrola incarnata Fisch with a green polyols based-deep eutectic solvent [J].
Yao, Xiao-Hui ;
Zhang, Dong-Yang ;
Duan, Ming-Hui ;
Cui, Qi ;
Xu, Wen-Jing ;
Luo, Meng ;
Li, Chun-Ying ;
Zu, Yuan-Gang ;
Fu, Yu-Jie .
SEPARATION AND PURIFICATION TECHNOLOGY, 2015, 149 :116-123