Synthesis, co-ordination chemistry and crystallographic studies of some bis(aminophosphines)

被引：60

作者：

Ly, TQ ^{[1
]}

Slawin, AMZ ^{[1
]}

Woollins, JD ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 09期

关键词：

D O I：

10.1039/a608141j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,2-Bis(diphenylphosphinoamino)benzene 1 and 3,4-bis(diphenylphosphinoamino)toluene 2 have been prepared; 1 is oxidised by sulfur or selenium to C6H4(NHPPh2S)(2)-1,2 3 and C6H4(NHPPh2Se)(2)-1,2 4 and by sulfur and selenium to C6H4(NHPPh2S)(NHPPh2Se)-1,2 5. The napthalene compounds C10H6(NHPPh2S)(2)-1,8 6, C10H6(NHPPh2Se)(2)-1,8 7, C10H6(NHPPh2S)(NHPPh2Se)-1,8 8 and the ethane compound C2H4(NHPPh2S)(2)-1,2 9 have also been prepared. The co-ordination of 2 to Mo-0, Pd-II, Pt-II and Au-I, i.e. in cis-[Mo(CO)(4)L], cis-[MCl2L] (M = Pd or Pt) and [(AuCl)(2)L] [L = MeC6H3(NHPPh2)(2)-3,4] is also described. The crystals structures of representative examples have been determined.

引用

页码：1611 / 1616

页数：6

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