Novel syntheses of Me2SbX (X = Cl, I) and crystal structures of Me2SbI and [(Me3Si)2CH]2SbCl

被引：0

作者：

Breunig, HJ ^{[1
]}

Althaus, H ^{[1
]}

Rösler, R ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 05期

关键词：

antimony; crystal structure;

D O I：

10.1002/(SICI)1521-3749(200005)626:5<1137::AID-ZAAC1137>3.0.CO;2-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures of Me2SbI (Me = CH3) and [(Me3Si)(2)CH](2)SbCl have been determined by X-ray methods. Both molecules are pyramidal. The Me2SbI molecules are associated to chains through short intermolecular Sb I distances (366,7(1) pm) with linear I-Sb I units (171,87(4)degrees) and bent Sb-I ... Sb bridges (116,83(3)degrees).

引用

页码：1137 / 1140

页数：4

共 24 条

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