Analysis of Parent/Nitrated Polycyclic Aromatic Hydrocarbons in Particulate Matter 2.5 Based on Femtosecond Ionization Mass Spectrometry

被引：11

作者：

Itouyama, Noboru ^{[1
]}

Matsui, Taiki ^{[1
]}

Yamamoto, Shigekazu ^{[2
]}

Imasaka, Tomoko ^{[3
]}

Imasaka, Totaro ^{[1
,4
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan

[2] Fukuoka Inst Hlth & Environm Sci, Dazaifu, Fukuoka 8180135, Japan

[3] Kyushu Univ, Grad Sch Design, Chem Lab, Minami Ku, Fukuoka 8158540, Japan

[4] Kyushu Univ, Div Optoelect & Photon, Ctr Future Chem, Nishi Ku, Fukuoka 8190395, Japan

来源：

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY | 2016年 / 27卷 / 02期

基金：

日本学术振兴会;

关键词：

Gas chromatography; Multiphoton ionization; Time-of-flight mass spectrometry; Particulate matter 2.5; Polycyclic aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; 2-DIMENSIONAL GAS-CHROMATOGRAPHY; ON-SITE ANALYSIS; MULTIPHOTON IONIZATION; STANDARD; DIOXIN; LASER; PAHS; 1-NITROPYRENE; SOOT; AIR;

D O I：

10.1007/s13361-015-1276-x

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Particulate matter 2.5 (PM2.5), collected from ambient air in Fukuoka City, was analyzed by gas chromatography combined with multiphoton ionization mass spectrometry using an ultraviolet femtosecond laser (267 nm) as the ionization source. Numerous parent polycyclic aromatic hydrocarbons (PPAHs) were observed in a sample extracted from PM2.5, and their concentrations were determined to be in the range from 30 to 190 pg/m(3) for heavy PPAHs. Standard samples of nitrated polycyclic aromatic hydrocarbons (NPAHs) were examined, and the limits of detection were determined to be in the picogram range. The concentration of NPAH adsorbed on PM2.5 in the air was less than 900-1300 pg/m(3).

引用

页码：293 / 300

页数：8

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