Sulfur-Catalyzed Stereo and Regioselective Synthesis of Heteropropellanes via Oxidative Condensation of Cyclohexanones with 2-Aminophenols

被引：13

作者：

Thanh Binh Nguyen ^{[1
]}

Retailleau, Pascal ^{[1
]}

机构：

[1] Univ Paris Saclay 1, Univ Paris Sud, CNRS, Inst Chim Subst Nat,UPR 2301, 1 Ave Terrasse, F-91198 Gif Sur Yvette, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2019年 / 361卷 / 15期

关键词：

sulfur; DMSO; heteropropellane; oxidative condensation; sulfur catalysis; ELEMENTAL SULFUR; PROPELLANES; ACCESS;

D O I：

10.1002/adsc.201900436

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Sulfur was found to be an excellent catalyst for the oxidative coupling of cyclohexanones with o-aminophenols using DMSO as oxidant. A wide range of heteropropellanes were obtained with complete regio and stereoselectivities and functional group tolerance.

引用

页码：3588 / 3592

页数：5

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